Dual fuel engine combustion utilizes a high-cetane fuel to initiate combustion of a low-cetane fuel. The performance and emissions benefits (low NOx and soot emissions) of dual fuel combustion are well-known. Ignition delay (ID) of the injected high-cetane fuel plays a critical role in quality of the dual fuel combustion process. This paper presents experimental analyses of the ID behavior for diesel-ignited propane and diesel-ignited methane dual fuel combustion. Two sets of experiments were performed at a constant engine speed (1800 rev/min) using a four-cylinder direct injection diesel engine with the stock electronic conversion unit (ECU) and a wastegated turbocharger. First, the effects of fuel–air equivalence ratios (Фpilot ∼ 0.2–0.6 and Фoverall ∼ 0.2–0.9) on IDs were quantified. Second, the effects of gaseous fuel percent energy substitution (PES) and brake mean effective pressure (BMEP) (from 2.5 to 10 bars) on IDs were investigated. With constant Фpilot (>0.5), increasing Фoverall with propane initially decreased ID but eventually led to premature propane auto-ignition; however, the corresponding effects with methane were relatively minor. Cyclic variations in the start of combustion (SOC) increased with increasing Фoverall (at constant Фpilot) more significantly for propane than for methane. With increasing PES at constant BMEP, the ID showed a nonlinear trend (initially increasing and later decreasing) at low BMEPs for propane but a linearly decreasing trend at high BMEPs. For methane, increasing PES only increased IDs at all BMEPs. At low BMEPs, increasing PES led to significantly higher cyclic SOC variations and SOC advancement for both propane and methane. Finally, the engine ignition delay (EID), defined as the separation between the start of injection (SOI) and the location of 50% of the cumulative heat release, was also shown to be a useful metric to understand the influence of ID on dual fuel combustion. Dual fuel ID is profoundly affected by the overall equivalence ratio, pilot fuel quantity, BMEP, and PES. At high equivalence ratios, IDs can be quite short, and beyond a certain limit, can lead to premature auto-igniton of the low-cetane fuel (especially for a reactive fuel like propane). Therefore, it is important to quantify dual fuel ID behavior over a range of engine operating conditions.