Research Papers: Fuel Combustion

Comparison Between RCCE and Shock Tube Ignition Delay Times at Low Temperatures

[+] Author and Article Information
Ghassan Nicolas, Hameed Metghalchi

Department of Mechanical
and Industrial Engineering,
Northeastern University,
Boston 02115, MA

Contributed by the Advanced Energy Systems Division of ASME for publication in the JOURNAL OF ENERGY RESOURCES TECHNOLOGY. Manuscript received April 16, 2015; final manuscript received April 21, 2015; published online June 16, 2015. Assoc. Editor: Reza H. Sheikhi.

J. Energy Resour. Technol 137(6), 062203 (Nov 01, 2015) (4 pages) Paper No: JERT-15-1151; doi: 10.1115/1.4030493 History: Received April 16, 2015; Revised April 21, 2015; Online June 16, 2015

The rate-controlled constrained-equilibrium (RCCE) method is a reduction technique based on local maximization of entropy or minimization of a relevant free energy at any time during the nonequilibrium evolution of the system subject to a set of kinetic constraints. In this paper, RCCE has been used to predict ignition delay times of low temperatures methane/air mixtures in shock tube. A new thermodynamic model along with RCCE kinetics has been developed to model thermodynamic states of the mixture in the shock tube. Results are in excellent agreement with experimental measurements.

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Nicolas, G., Janbozorgi, M., and Metghalchi, H., 2014, “Constrained-Equilibrium Modeling of Methane Oxidation in Air,” ASME J. Energy Resour. Technol., 136(3), p. 032205. [CrossRef]
Keck, J. C., and Gillespie, D., 1971, “Rate-Controlled Partial-Equilibrium Method for Treating Reacting Gas Mixtures,” Combust. Flame, 17(2), pp. 237–241. [CrossRef]
Keck, J. C., 1990, “Rate-Controlled Constrained-Equilibrium Theory of Chemical Reactions in Complex Systems,” Prog. Energy Combust. Sci., 16(2), pp. 125–154. [CrossRef]
Janbozorgi, M., Ugarte, S., Metghalchi, M., and Keck, J. C., 2009, “Combustion Modeling of Mono-Carbon Fuels Using the Rate-Controlled Constrained-Equilibrium Method,” Combust. Flame, 156(10), pp. 1871–1885. [CrossRef]
Law, R., Metghalchi, M., and Keck, J. C., 1988, “Rate-Controlled Constraint Equilibrium Calculations of Ignitin Delay Times in Hydrogen-Oxygen Mixtures,” 22nd Symposium (International) on Combustion, The Combustion Institute, Pittsburgh, p. 1705.
Bishnu, P., Hamiroune, D., Metghalchi, M., and Keck, J. C., 1997, “Constrained-Equilibrium Calculations for Chemical Systems Subject to Generalized Linear Constraints Using the NASA and STANJAN Equilibrium Programs,” Combust. Theory Model., 1, pp. 295–312. [CrossRef]
Hamiroune, D., Bishnu, P., Metghalchi, M., and Keck, J. C., 1998, “Rate-Controlled Constrained-Equilibrium Method Using Constraint Potentials,” Combust. Theory Model., 2, pp. 81–94. [CrossRef]
Ugarte, S., Gao, Y., and Metghalchi, M., 2005, “Application of the Maximum Entropy Principle in the Analysis of a Non-Equilibrium Chemically Reacting Mixture,” Int. J. Thermodyn., 3, pp. 43–53.
Janbozorgi, M., Gao, Y., Metghalchi, M., and Keck, J. C., 2006, Proceedings of the ASME (Int.), Chicago, Nov. 5–10.
Nicolas, G., Janbozorgi, M., and Metghalchi, M., 2014, “Constrained-Equilibrium Modeling of Methane Oxidation in Air,” ASME J. Energy Resour. Technol., 136(3), p. 032205. [CrossRef]
Chaos, M., and Dryer, F. L., 2010, “Chemical-Kinetic Modeling of Ignition Delays: Considerations in Interpreting Shock Tube Data,” Int. J. Chem. Kinet., 42(3), pp. 143–150. [CrossRef]
Frenklach, M., Li Kwok Cheong, C. K., and Oran, E. S., 1984, “LDV Measurement of Gas Flow Behind Reflected Shocks,” Prog. Astronaut. Aeronaut., 95, pp. 722–735.
Michael, J. V., and Sutherland, J. W., 1986, “The Thermodynamic State of the Hot Gas Behind Reflected Shock Waves: Implication to Chemical Kinetics,” Int. J. Chem. Kinet., 18(4), pp. 409–436. [CrossRef]
Petersen, E. L., and Hanson, R. K., 2001, “Nonideal Effects Behind Reflected Shock Waves in a High-Pressure Shock Tube,” Shock Waves, 10(6), pp. 405–420. [CrossRef]
Davidson, D. F., and Hanson, R. K., 2004, “Interpreting Shock Tube Ignition Data,” Int. J. Chem. Kinet., 36(9), pp. 510–523. [CrossRef]
Blumenthal, R., Fieweger, K., Komp, K. H., and Adomeit, G., 1996, “Gas Dynamic Features of Self Ignition of Non Diluted Fuel/Air Mixtures at High Pressure,” Combust. Sci. Technol., 113(1), pp. 137–166. [CrossRef]
Wang, B. L., Olivier, H., and Grönig, H., 2003, “Ignition of Shock-Heated H2-Air-Steam Mixtures,” Combust. Flame, 133(1–2), pp. 93–106. [CrossRef]
Furutani, M., Kitaguchi, Y., Yamada, T., and Ohta, Y., 1999, Proceedings of the 17th ICDERS, University of Heidelberg, Heidelberg, Germany.
Furutani, M., Ohta, Y., Kitaguchi, Y., Osaki, M., Murai, M., and Isogai, T., 2001, “Shock-Compression Low-Temperature Ignition and Its Peculiarity,” Trans. Jpn. Soc. Mech. Eng. B, 67(662), pp. 2625–2631. [CrossRef]
Dryer, F. L., and Chaos, M., 2008, “Ignition of Syngas/Air and Hydrogen/Air Mixtures at Low Temperatures and High Pressures: Experimental Data Interpretation and Kinetic Modeling Implications,” Combust. Flame, 152(1–2), pp. 293–299. [CrossRef]
Chaos, M., and Dryer, F. L., 2008, “Syngas Combustion Kinetics and Applications,” Combust. Sci. Technol., 180(6), pp. 1051–1094. [CrossRef]
Chaos, M., Burke, M. P., Ju, Y., Dryer, F. L., In Lieuwen, T. C., Yang, V., and Yetter, R. A. eds., 2010, Synthesis Gas Combustion: Fundamentals and Applications, CRC Press, Boca Raton, FL, Chap. 2.
Pfahl, U., Fieweger, K., and Adomeit, G., 1996, “Self-Ignition of Diesel-Relevant Hydrocarbon-Air Mixtures Under Engine Conditions,” Proc. Combust. Inst., 26(1), pp. 781–789. [CrossRef]
Misawa, S., Shiraishi, N., Kosaka, H., and Matsui, Y., 2001, Nihon Kikai Gakkai Nenji Taikai Koen Ronbunshu, 2, pp. 519–520.
Davidson, D. F., Gauthier, B. M., and Hanson, R. K., 2005, “Shock Tube Ignition Measurements of Iso-Octane/Air and Toluene/Air at High Pressures,” Proc. Combust. Inst., 30(1), pp. 1175–1182. [CrossRef]
Reehal, S. C., Kalitan, D. M., Hair, T., Barrett, A. B., and Petersen, E. L., 2007, “Ignition Delay Time Measurement of Synthesis Gas Mixture at Engine Pressures,” Proceedings of the 5th U.S. Combustion Meeting, San Diego, CA, Paper No. C24.
Stranic, I., Chase, D., Harmon, J. T., Yang, S., Davidson, D. F., and Hanson, R. K., 2012, “Shock Tube Measurements of Ignition Delay Times for Butanol Isomers,” Combust. Flame, 159(2) pp. 516–527 [CrossRef]
Li, H., Owens, Z. C., Davidson, D. F., and Hanson, R. K., 2008, “A Simple Reactive Gasdynamic Model for the Computation of Gas Temperature and Species Concentrations Behind Reflected Shock Waves,” Int. J. Chem. Kin., 40(4), pp. 89–98.
Huang, J., Hill, P. G., Bushe, W. K., and Munshi, S. R., 2004, “Shock-Tube Study of Methane Ignition Under Engine-Relevant Conditions: Experiments and Modeling,” Combust. Flame, 136(1–2), pp. 25–42. [CrossRef]


Grahic Jump Location
Fig. 1

A typical prescribed pressure profile for CH4/air mixture in shock tube

Grahic Jump Location
Fig. 2

Comparison of ignition delay times between RCCE and shock tube experiments [29] with a prescribed pressure profile with τ = 0.7 ms and α = 4%/ms. Initial conditions are: Phi = 1.0 and P = 23 atm and temperature varying from 1076 to 1309 K.

Grahic Jump Location
Fig. 3

C1 chemistry-comparison in ignition delay time between RCCE and shock tube experiments [29] with a prescribed pressure profile with τ = 0.6 ms and α = 5%/ms. Initial conditions are Phi = 1.0, P = 40 atm, and temperature varying from 1085 to 1290 K.




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