Research Papers: Petroleum Engineering

Study and Use of Geopolymer Mixtures for Oil and Gas Well Cementing Applications

[+] Author and Article Information
Saeed Salehi, C. Ezeakacha, Fatemeh K. Saleh

Mewbourne School of Petroleum
and Geological Engineering,
University of Oklahoma,
Norman, OK 73069

Mohammad Jamal Khattak

Civil Engineering Department,
University of Louisiana,
Lafayette, LA 70504

Nasir Ali

Petroleum Engineering Department,
University of Louisiana,
Lafayette, LA 70504

Contributed by the Petroleum Division of ASME for publication in the JOURNAL OF ENERGY RESOURCES TECHNOLOGY. Manuscript received June 16, 2017; final manuscript received July 24, 2017; published online September 12, 2017. Editor: Hameed Metghalchi.

J. Energy Resour. Technol 140(1), 012908 (Sep 12, 2017) (12 pages) Paper No: JERT-17-1290; doi: 10.1115/1.4037713 History: Received June 16, 2017; Revised July 24, 2017

The study here presents laboratory testing results of Class F fly ash geopolymer for oil well cementing applications. The challenge reported in literature for the short thickening time of geopolymer ash has been overcome in this study, where more than 5 h of the thickening time is achievable. API Class H Portland cement used a controller on all the tests conducted in this work. Tests conducted in this research include unconfined compressive strength (UCS), shear bond strength, thickening time, shrinkage, free water, and cyclic and durability tests. Results indicate temperature as a crucial factor affecting the thickening time of geopolymer mix slurry. UCS testing indicates considerably higher compressive strength after one and fourteen days of curing for geopolymer mixtures. This indicates gaining strength with time for geopolymer mixture, where time retrogression effects are observed for Portland cements. Results also indicate higher shear bond strength for geopolymer mix that can better tolerate debonding issues. Additionally, more ductile material behavior and higher fracture toughness were observed for optimum geopolymer mixes. Tests also show applicability of these materials for deviated wells as a zero free water test was observed.

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Wang, Y. , and Salehi, S. , 2015, “ Application of Real-Time Field Data to Optimize Drilling Hydraulics Using Neural Network Approach,” ASME J. Energy Resour. Technol., 137(6), p. 062903. [CrossRef]
Farahani, M. , Soleimani, R. , Jamshidi, S. , and Salehi, S. , 2014, “ Development of a Dynamic Model for Drilling Fluid's Filtration: Implications to Prevent Formation Damage,” SPE International Symposium and Exhibition on Formation Damage Control, Lafayette, LA, Feb. 26–28, SPE Paper No. SPE-168151-MS.
Dokhani, V. , Pordel Shahri, M. , Karimi, M. , and Salehi, S. , 2013, “ Evaluation of Annular Pressure Losses While Casing Drilling,” SPE Annual Technical Conference and Exhibition, New Orleans, LA, Sept. 30–Oct. 2, SPE Paper No. SPE-166103-MS.
Salehi, S. , and Kiran, R. , 2016, “ Integrated Experimental and Analytical Wellbore Strengthening Solutions by Mud Plastering Effects,” ASME J. Energy Resour. Technol., 138(3), p. 032904. [CrossRef]
Ghalambor, A. , Salehi, S. , Shahri, M. P. , and Karimi, M. , 2014, “ Integrated Workflow for Lost Circulation Prediction,” SPE International Symposium and Exhibition on Formation Damage Control, Lafayette, LA, Feb. 26–28, SPE Paper No. SPE-168123-MS.
Sabins, F. L. , 1990, “ Problems in Cementing Horizontal Wells,” J. Pet. Technol., 42(4), pp. 398–400.
Manowski, W. M. , and Wojtanowicz, A. K. , 1998, “ Oilwell Cement Pulsing to Maintain Hydrostatic Pressure—A Search for Design Model,” ASME J. Energy Resour. Technol., 120(4), pp. 250–255. [CrossRef]
Ravi, K. , Biezen, E. N. , Lightford, S. C. , Hibbert, A. , and Greaves, C. , 1999, “ Deepwater Cementing Challenges,” SPE Annual Technical Conference and Exhibition, Houston, TX, Oct. 3–6, SPE Paper No. SPE-56534-MS.
Sweatman, R. , 2000, “ Overview: Cementing Technology,” J. Pet. Technol., 57(8), p. 40.
Stiles, D. , and Hollies, D. , 2002, “ Implementation of Advanced Cementing Techniques to Improve Long Term Zonal Isolation in Steam Assisted Gravity Drainage Wells,” SPE International Thermal Operations and Heavy Oil Symposium and International Horizontal Well Technology Conference, Calgary, AB, Canada, Nov. 4–7, SPE Paper No. SPE-78950-MS.
Rusch, D. W. , Sabins, F. , and Aslakson, J. , 2004, “ Microannulus Leaks Repaired With Pressure-Activated Sealant,” SPE Eastern Regional Meeting, Charleston, WV, Sept. 15–17, SPE Paper No. SPE-91399-MS.
Cowan, M. , 2007, “ Field Study Results Improve Squeeze Cementing Success,” Production and Operations Symposium, Oklahoma City, OK, Mar. 31–Apr. 3, SPE Paper No. SPE-106765-MS.
Zhou, D. , and Wojtanowicz, A. K. , 2009, “ Cement Seal Failure at Casing Shoe in Shallow Marine Sediments,” ASME J. Energy Resour. Technol., 131(2), p. 023101. [CrossRef]
Zhou, D. , and Wojtanowicz, A. K. , 2011, “ Annular Pressure Reduction During Primary Cementing,” ASME J. Energy Resour. Technol., 133(3), p. 031003. [CrossRef]
Aughenbaugh, K. , Nair, S. D. , Cowan, K. , and van Oort, E. , 2014, “ Contamination of Deepwater Well Cementations by Synthetic-Based Drilling Fluids,” SPE Deepwater Drilling and Completions Conference, Galveston, TX, Sept. 10–11, SPE Paper No. SPE-170325-MS.
Taleghani, A. D. , Li, G. , and Moayedi, M. , 2017, “ Smart Expandable Cement Additive to Achieve Better Wellbore Integrity,” ASME J. Energy Resour. Technol., 139(6), p. 062903. [CrossRef]
Davidovits, J. , 1994, “ High-Alkali Cements for 21st Century Concretes,” Mohan Malhotra Symposium on Concrete Technology: Past, Present and Future, Berkeley, CA, Nov. 3, pp. 383–397. https://www.concrete.org/publications/internationalconcreteabstractsportal/m/details/id/4523
Bourlon, A. , 2010, “ Physico-Chimie et Rhéologie de Géopolymères Frais Pour la Cimentation des Puits Pétrolier,” Ph.D. dissertation, Université Pierre et Marie Curie-Paris VI, Paris, France.
Khalifeh, M. , Saasen, A. , Vralstad, T. , and Hodne, H. , 2014, “ Potential Utilization of Geopolymers in Plug and Abandonment Operations,” SPE Bergen One Day Seminar, Bergen, Norway, Apr. 2, SPE Paper No. 169231.
Shah, S. , and Jeong, Y. , 2003, “ The Flow Characteristics of Fly Ash Slurry for Plugging Abandoned Wells Using Coiled Tubing,” International Ash Utilization Symposium, Lexington, KY, Oct. 20–22, Paper No. 10 http://www.flyash.info/2003/110sha.pdf.
Salehi, S. , Khattak, M. J. , Bwala, A. H. , and Karbalaei, S. F. , 2017, “ Characterization, Morphology and Shear Bond Strength Analysis of Geopolymers: Implications for Oil and Gas Well Cementing Applications,” J. Nat. Gas Sci. Eng., 38, pp. 323–332. [CrossRef]
Salehi, S. , Khattak, M. J. , Rizvi, H. , Karbalaei, S. F. , and Kiran, R. , 2017, “ Sensitivity Analysis of Fly Ash Geopolymer Cement Slurries: Implications for Oil and Gas Wells Cementing Applications,” J. Nat. Gas Sci. Eng., 37, pp. 116–125. [CrossRef]
Jackson, P. B. , and Murphey, C. E. , 1993, “ Effect of Casing Pressure on Gas Flow Through a Sheath of Set Cement,” SPE/IADC Drilling Conference, Amsterdam, The Netherlands, Feb. 22–25, SPE Paper No. SPE-25698-MS.
Goodwin, K. J. , and Crook, R. J. , 1992, “ Cement Sheath Stress Failure,” SPE Drill. Eng. J., 7(4), pp. 291–296. [CrossRef]
Brady, J. L. , Gnatt, L. L. , Fife, D. M. , Rich, D. A. , Almond, S. W. , and Ross, D. A. , 1989, “ Cement Solubility in Acids,” Low Permeability Reservoirs Symposium, Denver, CO, Mar. 6–8, SPE Paper No. SPE-18986-MS.
Krilov, Z. , Loncaric, B. , and Miksa, Z. , 2000, “ Investigation of a Long-Term Cement Deterioration Under a High-Temperature, Sour Gas Downhole Environment,” SPE International Symposium on Formation Damage Control, Lafayette, LA, Feb. 23–24, SPE Paper No. SPE-58771-MS.
Backe, K. R. , Lile, O. B. , Lyomov, S. K. , Elvebakk, H. , and Skalle, P. , 1997, “ Characterising Curing Cement Slurries by Permeability, Tensile Strength and Shrinkage,” SPE Western Regional Meeting, Long Beach, CA, June 25–27, SPE Paper No. SPE-38267-MS.
Duguid, A. , 2008, “ The Effect of Carbonic Acid on Well Cements as Identified Through Lab and Field Studies,” SPE Eastern Regional/AAPG Eastern Section Joint Meeting, Pittsburgh, PA, Oct. 11–15, SPE Paper No. SPE-119504-MS.
Lecolier, E. , Riverean, A. , Ferrier, N. , Audibert, A. , and Longaygue, X. , 2008, “ Study of New Solutions for Acid-Resistant Cements,” SPE Annual Technical Conference and Exhibition, Denver, CO, Sept. 21–24, SPE Paper No. SPE-116066-MS.
Koenders, E. A. , Hansen, W. , Ukrainczyk, N. , and Toledo Filho, R. D. , 2014, “ Modeling Pore Continuity and Durability of Cementitious Sealing Material,” ASME J. Energy Resour. Technol., 136(4), p. 042904. [CrossRef]
Rangan, B. V. , 2010, “ Fly Ash Based Geopolymer Concrete,” International Workshop on Geopolymer Cement and Concrete, Chennai, India, Dec. 7, pp. 68–106. https://www.researchgate.net/publication/230717147_Fly_Ash-Based_Geopolymer_Concrete
Xu, H. , and Van Deventer, J. S. J. , 2000, “ The Geopolymerisation of Alumino-Silicate Minerals,” Int. J. Mineral Process., 59(3), pp. 247–266. [CrossRef]
Palomo, A. , Grutzeck, M. W. , and Blanco, M. T. , 1999, “ Alkali Activated Fly Ashes: A Cement for the Future,” Cem. Concr. Res., 29(8), pp. 1323–1329. [CrossRef]
Mendes, A. , Sanjayan, J. , and Collins, F. , 2008, “ Phase Transformation and Mechanical Strength of OPC/Slag Pastes Submitted to Higher Temperatures,” Mater. Struct., 41(2), pp. 345–350. [CrossRef]
Nasvi, M. , Ranjith, P. , and Sanjayan, J. , 2012, “ Comparison of Mechanical Behaviors of Geopolymer and Class G Cement as Well Cement at Different Curing Temperatures for Geological Sequestration of Carbon Dioxide,” 46th U.S. Rock Mechanics/Geomechanics Symposium, Chicago, IL, June 24–27, Paper No. ARMA 2012-232. https://www.onepetro.org/conference-paper/ARMA-2012-232
Uehara, M. , 2010, “ New Concrete With Low Environmental Load Using the Geopolymer Method,” Quart. Rep. RTRI, 51(1), pp. 1–7. [CrossRef]
Neetu, S. , Sameer, V. , Pathak, R. P. , Pankaj, S. , Mahure, N. V. , and Gupta, S. L. , 2013, “ Effect of Aggressive Chemical Environment on Durability of Green Geopolymer Concrete,” Int. J. Eng. Innovative Technol., 3(4), pp. 277–284. http://www.ijeit.com/Vol%203/Issue%204/IJEIT1412201310_49.pdf
Provis, J. L. , and Jannie, S. J. V. D. , 2009, Geopolymers: Structure, Processing, Properties and Industrial Applications, Woodhead Publishing Limited/CRC Press, New Delhi, India/Boca Raton, FL.
Shi, C. , Roy, D. , and Krivenko, P. , 2006, Alkali-Activated Cements and Concrete, Taylor and Francis, New York. [CrossRef] [PubMed] [PubMed]
Barbosa, V. F. F. , MacKenzie, K. J. D. , and Thaumaturgo, C. , 2000, “ Synthesis and Characterisation of Materials Based on Inorganic Polymers of Alumina and Silica: Sodium Polysialate Polymers,” Int. J. Inorg. Mater., 2(4), pp. 309–317. [CrossRef]
Pacheco-Torgal, F. , Castro-Gomes, J. , and Jalali, S. , 2008, “ Alkali-Activated Binders: A Review—Part I: Historical Background, Terminology, Reaction Mechanisms and Hydration Products,” J. Constr. Build. Mater., 22(7), pp. 1305–1314. [CrossRef]
API 10b, 2013, “ API Recommended Practice 10B-2, Recommended Practice for Testing Well Cements,” American Petroleum Institute, Washington, DC, Standard No. API RP 10B-2. http://www.techstreet.com/standards/api-rp-10b-2?product_id=1855370
Santra, A. K. , Reddy, B. R. , Liang, F. , and Fitzgerald, R. , 2009, “ Reaction of CO2 With Portland Cement at Downhole Conditions and the Role of Pozzolanic Supplements,” SPE International Symposium on Oilfield Chemistry, Woodlands, TX, Apr. 20–22, SPE Paper No. SPE-121103-MS.
Chenevert, M. E. , and Shrestha, B. K. , 1991, “ Chemical Shrinkage Properties of Oilfield Cements,” SPE Drill. Completion, 6(1), pp. 37–43. [CrossRef]
Reddy, B. R. , Xu, Y. , Ravi, K. , Gray, D. W. , and Pattillo, P. , 2009, “ Cement Shrinkage Measurement in Oilwell Cementing—A Comparative Study of Laboratory Methods and Procedures,” SPE Drill. Completion, 24(1), pp. 104–114.
Nygaard, R. , Salehi, S. , Weideman, B. , and Lavoie, R. , 2014, “ Effect of Dynamic Loading on Wellbore Leakage for the Wabamun Area CO2 Sequestration Project,” J. Can. Pet. Technol., 53(1), pp. 69–82. [CrossRef]
Carter, L. , and Evans, G. , 1964, “ A Study of Cement-Pipe Bonding,” J. Pet. Technol., 16(2), pp. 157–160. [CrossRef]


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Fig. 1

Dissolution and reaction process of geopolymer binder [36]

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Fig. 2

Shear bond strength setup (left) and casing pipes used for shear bond strength tests (with and without mill varnish)

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Fig. 3

(a) Shrinkage assembly and (b) sample ready for measurement

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Fig. 4

The HPHT Consistometer used in the experiments

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Fig. 11

The thickening time results for the comparison of the base mix, and the mix with the addition of superplasticizer and retarder

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Fig. 10

The thickening time comparison for slurries at different temperatures

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Fig. 9

Gelling around paddle for slurries tested at high temperature without addition of superplasticizer (left), and sample at end of testing (right)

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Fig. 8

The thickening time test results of the slurry at 200 °F with and without addition of retarder/plasticizer

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Fig. 7

UCS comparison at different curing temperatures

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Fig. 6

Comparison of UCS for geopolymer samples with API Class H Portland cement in 14 days curing time

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Fig. 5

(a) Effect of molarity of alkaline on fly ash slurry UCS and (b) the effect of silicates to hydroxide ratio on UCS

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Fig. 12

(a) SEM image of API Class H cement slurry (left) and (b) image of fly ash geopolymer mix (right)

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Fig. 13

Shrinkage results comparison for API Class H and fly ash sample for 10 days (150 °F and 200 °F)

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Fig. 14

Shear stress–displacement shear load for fly ash geopolymer, compared with API Class H cement

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Fig. 15

Contamination test results of cement and geopolymer

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Fig. 16

Detailed view of the free fluid test at 45 deg inclination (left: Portland cement; right: geopolymer)

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Fig. 17

Fly ash geopolymer cured at 150 °F and 3000 psi divided into five unequal portions

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Fig. 18

The thickening time test results for mixture at 150 °F

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Fig. 19

The thickening time test results for mixture at 200 °F

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Fig. 20

The thickening time test results for a mixture at 250 °F with no retarder

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Fig. 21

The thickening time test results for a mixture at 250 °F with retarder



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