Special Section on 2018 Clean Energy

Evaluating Laser-Induced Breakdown Spectroscopy Sensor Technology for Rapid Source Characterization of Rare Earth Elements

[+] Author and Article Information
Daniel A. Hartzler, Chet R. Bhatt, Jinesh C. Jain

National Energy Technology Laboratory,
U.S. Department of Energy,
Pittsburgh, PA 15236;
Leidos Research Support Team,
National Energy Technology Laboratory,
Pittsburgh, PA 15236

Dustin L. McIntyre

National Energy Technology Laboratory,
U.S. Department of Energy,
Morgantown, WV 26505
e-mail: Dustin.Mcintyre@netl.doe.gov

1Corresponding author.

Contributed by the Advanced Energy Systems Division of ASME for publication in the JOURNAL OF ENERGY RESOURCES TECHNOLOGY. Manuscript received August 21, 2018; final manuscript received February 1, 2019; published online March 11, 2019. Assoc. Editor: Ashwani K. Gupta.The United States Government retains, and by accepting the article for publication, the publisher acknowledges that the United States Government retains, a nonexclusive, paid-up, irrevocable, worldwide license to publish or reproduce the published form of this work, or allow others to do so, for United States government purposes.

J. Energy Resour. Technol 141(7), 070704 (Mar 11, 2019) (7 pages) Paper No: JERT-18-1643; doi: 10.1115/1.4042747 History: Received August 21, 2018; Revised February 01, 2019

A prototype laser-induced breakdown spectroscopy (LIBS) sensor is tested for the determination of rare earth elements (Eu and Yb) in liquid and solid samples. The sensor head, built using a monolithic passively Q-switched (PQSW) Nd:YAG laser, produced a 1064 nm laser beam with ns pulses and an energy of 4.2 mJ. The measurements show good calibration linearity for both Eu and Yb with R2 values above 0.99 for all analyzed spectral lines in liquid and solid samples. Limits of detection (LODs) obtained were as low as 1 ppm, which are comparable to or better than those reported previously by using table top actively Q-switched systems. This study aims to develop a high sensitivity, field deployable sensor for characterizing existing and new sources of rare earth elements.

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Grahic Jump Location
Fig. 1

Schematic layout of LIBS sensor head. Pump telescope L1 = 6.2 mm and L2 = 11 mm aspheric lenses, beam expander L3 = −25 mm and L4 = 75 mm, aspheric focusing lens L5 = 10 mm, emission coupling lens L5 and L6 = 25 mm. DCM = 900 nm longwave pass dichroic mirror, M = aluminum mirror, BP = 1064 nm bandpass filter, PD = photodiode.

Grahic Jump Location
Fig. 2

Liquid solution SBR of spectral lines of Yb and Eu as a function of gate delay. Dashed lines are exponential fits to the decay curves from 200 to 1000 ns.

Grahic Jump Location
Fig. 3

Solid pellet SBR for a 10,000 ppm Eu pellet as a function of gate delay. Dashed lines are exponential fits to the decay curves from 2.5–10 ps.

Grahic Jump Location
Fig. 4

Liquid solution LIBS emission spectra and calibration curves of three atomic emission lines of Eu (a) and one atomic line of Yb (b). Spectra are of the 1000 ppm Eu or Yb samples. Error bars are twice the standard deviation of eight repeated measurements.

Grahic Jump Location
Fig. 5

Solid pellet LIBS emission spectra and calibration curves of three atomic emission lines and four ionic lines of Eu. Spectrum is obtained using the pellet containing 2500 ppm Eu. Error bars are one standard deviation of eight repeated measurements. Note that Fig. 4 uses two standard deviations instead of one. This was chosen for figure readability.



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