Self-assembly of carbon nanotubes (CNTs) on silicon substrates has myriad applications including nanotube based electrochemical energy conversion and storage devices, such as batteries and super-capacitors. Patterned assembly of CNTs is required in order to control the effective electrical conductivity and mechanical properties of these devices and achieve substantial improvement in their performance. Solution-based self-assembly of CNTs provides a cost-effective means to synthesize uniform vertically or horizontally aligned nanostructures on top of substrates. However, self-assembly of CNTs is a complex dynamical process that involves intermolecular interaction between the CNTs and that between the nanotubes and the substrate as well as solvent molecules. The transport properties of CNTs and solvents also play an important role. The scientific literature lacks detailed study of understanding the mechanism of self-assembly of CNTs on substrates during synthesis process. Often times, nanotubes are functionalized in an effort to make them more soluble and induce partial charges to control the self-assembly. Some of the key factors that govern the transportation and self-assembly of functionalized CNTs are surface charge density on substrate and electrostatic interaction of the functionalized CNTs with the substrate. In an effort to mimic the conditions during the synthesis of carbon nanomaterials on silicon substrate, we have employed molecular dynamics simulations to simulate both pure and functionalized CNTs sandwiched between silicon substrates in presence of commonly used solvent, water. Our simulations indicate that both pure and functionalized CNTs are not significantly soluble in water and form agglomerates. Our results also illustrate that neither pure nor functionalized CNTs tend to deposit on silicon substrates in water. Results presented in this study provide fundamental insight that can help to understand the agglomeration and orientation of CNTs in water.
Skip Nav Destination
ASME 2013 International Mechanical Engineering Congress and Exposition
November 15–21, 2013
San Diego, California, USA
Conference Sponsors:
- ASME
ISBN:
978-0-7918-5629-1
PROCEEDINGS PAPER
Controlled Self-Assembly of Functionalized Carbon Nanotubes on Silicon Substrates
S. M. Mortuza,
S. M. Mortuza
Washington State University, Pullman, WA
Search for other works by this author on:
Soumik Banerjee
Soumik Banerjee
Washington State University, Pullman, WA
Search for other works by this author on:
S. M. Mortuza
Washington State University, Pullman, WA
Soumik Banerjee
Washington State University, Pullman, WA
Paper No:
IMECE2013-66579, V06BT07A043; 7 pages
Published Online:
April 2, 2014
Citation
Mortuza, SM, & Banerjee, S. "Controlled Self-Assembly of Functionalized Carbon Nanotubes on Silicon Substrates." Proceedings of the ASME 2013 International Mechanical Engineering Congress and Exposition. Volume 6B: Energy. San Diego, California, USA. November 15–21, 2013. V06BT07A043. ASME. https://doi.org/10.1115/IMECE2013-66579
Download citation file:
11
Views
Related Proceedings Papers
Related Articles
Carbon Nanotube-Based Sensors for Detection of Gas Atoms
J. Nanotechnol. Eng. Med (May,2011)
Carbon Nanotubes, Synthesis, Growth and Orientation Control in Opposed Flow Diffusion Flames
J. Heat Transfer (April,2008)
Ion Storage in Nanoconfined Interstices Between Vertically Aligned Nanotubes in Electric Double-Layer Capacitors
J. Electrochem. En. Conv. Stor (February,2018)
Related Chapters
Characterization and evaluation
Biocompatible Nanomaterials for Targeted and Controlled Delivery of Biomacromolecules
Off-Site Fabrication and Assembly
Consensus on Pre-Commissioning Stages for Cogeneration and Combined Cycle Power Plants
Challenges in biomacromolecular delivery
Biocompatible Nanomaterials for Targeted and Controlled Delivery of Biomacromolecules