Research Papers: Petroleum Engineering

Mobilization of Crude Oil in Porous Media With Oil-Soluble Surfactant Delivered by Hydrosoluble Micelles

[+] Author and Article Information
Chike G. Ezeh, Yufei Duan

Department of Chemical &
Biomolecular Engineering,
Tulane University,
New Orleans, LA 70118

Riccardo Rausa

Eni S.p.A., Upstream and Technical Services,
San Donato M.se Res., Center,
San Donato Milanese, 20097, Italy

Kyriakos D. Papadopoulos

Department of Chemical &
Biomolecular Engineering,
Tulane University,
New Orleans, LA 70118
e-mail: kyriakos@tulane.edu

1Chike G. Ezeh and Yufei Duan contributed equally to this work.

2Corresponding author.

Contributed by the Petroleum Division of ASME for publication in the JOURNAL OF ENERGY RESOURCES TECHNOLOGY. Manuscript received March 16, 2018; final manuscript received August 2, 2018; published online September 14, 2018. Assoc. Editor: Daoyong (Tony) Yang.

J. Energy Resour. Technol 141(3), 032902 (Sep 14, 2018) (10 pages) Paper No: JERT-18-1211; doi: 10.1115/1.4041094 History: Received March 16, 2018; Revised August 02, 2018

In this work, an oil-soluble surfactant was studied to enhance crude oil mobilization in a cryolite-packed miniature bed. The cryolite packed bed provided a transparent, random porous medium for observation at the microscopic level. In the first part of the paper, oil-soluble surfactants, Span 80 and Eni-surfactant (ES), were dissolved directly into the crude oil. The porous medium was imbued with the crude oil (containing the surfactants), and de-ionized water was the flooding phase; in this experiment, the system containing ES had the best performance. Subsequently, sodium dodecyl sulfate (SDS), a hydrosoluble surfactant, was used to solubilize the ES, with the SDS acting as a carrier for the ES to the contaminated porous media. Finally, the SDS/ES micellar solutions were used in oil-removal tests on the packed bed. Grayscale image analysis was used to quantify the oil recovery effectiveness for the flooding experiments by measuring the white pixel percentage in the packed bed images. The SDS/ES flooding mixture had a better performance than the SDS alone.

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Alvarado, V. , and Manrique, E. , 2010, “Enhanced Oil Recovery: An Update Review,” Energies, 3(9), pp. 1529–1575. [CrossRef]
Jelgersma, F. , 2007, “Redevelopment of the Abandoned Dutch Onshore Schoonebeek Oilfield With Gravity Assisted Steam Flooding,” International Petroleum Technology Conference, Dubai, United Arab Emirates, Dec. 4–6, Paper No. IPTC-11700-MS.
Lacerda, G. , d, M. , Patriota, J. H. , Pereira, J. I. , de Lima, L. A. , and Silva, T. J. , 2008, “Alto do Rodrigues GeDIg Pilot-Case Study for Continuous Steam Injection Recovery Combined With Real Time Operation,” Intelligent Energy Conference and Exhibition, Amsterdam, The Netherlands, Feb. 25–27, SPE Paper No. SPE-112242-MS.
Hossain, M. E. , 2018, “Dimensionless Scaling Parameters During Thermal Flooding Process in Porous Media,” ASME J. Energy Resour. Technol., 140(7), p. 072004.
Du, X. , Gu, M. , Duan, S. , and Xian, X. , 2018, “The Influences of CO2 Injection Pressure on CO2 Dispersion and the Mechanism of CO2–CH4 Displacement in Shale,” ASME J. Energy Resour. Technol., 140(1), p. 012907.
Hoffman, B. T. , and Shoaib, S. , 2014, “CO2 Flooding to Increase Recovery for Unconventional Liquids-Rich Reservoirs,” ASME J. Energy Resour. Technol., 136(2), p. 022801.
Le Van, S. , and Chon, B. H. , 2018, “Effective Prediction and Management of a CO2 Flooding Process for Enhancing Oil Recovery Using Artificial Neural Networks,” ASME J. Energy Resour. Technol., 140(3), p. 032906.
Pratap, M. , Roy, R. , Gupta, R. , and Singh, D. , 1997, “Field Implementation of Polymer EOR Technique—A Successful Experiment in India,” SPE Annual Technical Conference and Exhibition, San Antonio, TX, Oct. 5–8, SPE Paper No. SPE-38872-MS.
Liu, Q. , Dong, M. , Ma, S. , and Tu, Y. , 2007, “Surfactant Enhanced Alkaline Flooding for Western Canadian Heavy Oil Recovery,” Colloids Surf. A: Physicochem. Eng. Aspects, 293(1–3), pp. 63–71. [CrossRef]
Askarinezhad, R. , Hatzignatiou, D. G. , and Stavland, A. , 2018, “Core-Based Evaluation of Associative Polymers as Enhanced Oil Recovery Agents in Oil-Wet Formations,” ASME J. Energy Resour. Technol., 140(3), p. 032915.
Thomas, S. , 2008, “Enhanced Oil Recovery—An Overview,” Oil Gas Sci. Technol.-Revue De l'IFP, 63(1), pp. 9–19. [CrossRef]
Kong, X. , and Ohadi, M. , 2010, “Applications of Micro and Nano Technologies in the Oil and Gas Industry—Overview of the Recent Progress,” International Petroleum Exhibition and Conference, Abu Dhabi, UAE, Nov. 1–4, SPE Paper No. SPE-138241-MS.
Wong, K. V. , and De Leon, O. , 2010, “Applications of Nanofluids: Current and Future,” Adv. Mech. Eng., 2010(2), pp. 519659–519669. [CrossRef]
Ayatollahi, S. , and Zerafat, M. M. , 2012, “Nanotechnology-Assisted EOR Techniques: New Solutions to Old Challenges,” SPE International Oilfield Nanotechnology Conference and Exhibition, Noordwijk, The Netherlands, June 12–14, SPE Paper No. SPE-157094-MS.
Zhang, H. , Ramakrishnan, T. , Nikolov, A. , and Wasan, D. , 2016, “Enhanced Oil Recovery Driven by Nanofilm Structural Disjoining Pressure: Flooding Experiments and Microvisualization,” Energy Fuels, 30(4), pp. 2771–2779. [CrossRef]
Karimi, A. , Fakhroueian, Z. , Bahramian, A. , Pour Khiabani, N. , Darabad, J. B. , Azin, R. , and Arya, S. , 2012, “Wettability Alteration in Carbonates Using Zirconium Oxide Nanofluids: EOR Implications,” Energy Fuels, 26(2), pp. 1028–1036. [CrossRef]
Onyekonwu, M. O. , and Ogolo, N. A. , 2010, “Investigating the Use of Nanoparticles in Enhancing Oil Recovery,” Nigeria Annual International Conference and Exhibition, Tinapa–Calabar, Nigeria, July 31–Aug. 7, SPE Paper No. SPE-140744-MS.
McNutt, M. K. , Camilli, R. , Crone, T. J. , Guthrie, G. D. , Hsieh, P. A. , Ryerson, T. B. , Savas, O. , and Shaffer, F. , 2012, “Review of Flow Rate Estimates of the Deepwater Horizon Oil Spill,” Proc. Natl. Acad. Sci., 109(50), pp. 20260–20267. [CrossRef]
Zheng, M. , Wang, W. , Hayes, M. , Nydell, A. , Tarr, M. A. , Van Bael, S. A. , and Papadopoulos, K. , 2018, “Degradation of Macondo 252 Oil by Endophytic Pseudomonas putida,” J. Environ. Chem. Eng., 6(1), pp. 643–648. [CrossRef]
Dauvin, J. C. , 1998, “The Fine Sand Abra Alba Community of the Bay of Morlaix Twenty Years After the Amoco Cadiz Oil Spill,” Mar. Pollut. Bull., 36(9), pp. 669–676. [CrossRef]
Dauvin, J. , 2000, “The Muddy Fine Sand Abra Alba–Melinna Palmata Community of the Bay of Morlaix Twenty Years After the Amoco Cadiz Oil Spill,” Mar. Pollut. Bull., 40(6), pp. 528–536. [CrossRef]
Kingston, P. F. , 2002, “Long-Term Environmental Impact of Oil Spills,” Spill Sci. Technol. Bull., 7(1–2), pp. 53–61. [CrossRef]
Reddy, C. M. , Eglinton, T. I. , Hounshell, A. , White, H. K. , Xu, L. , Gaines, R. B. , and Frysinger, G. S. , 2002, “The West Falmouth Oil Spill After Thirty Years: The Persistence of Petroleum Hydrocarbons in Marsh Sediments,” Environ. Sci. Technol., 36(22), pp. 4754–4760. [CrossRef] [PubMed]
Peacock, E. E. , Nelson, R. K. , Solow, A. R. , Warren, J. D. , Baker, J. L. , and Reddy, C. M. , 2005, “The West Falmouth Oil Spill:∼ 100 Kg of Oil Found to Persist Decades Later,” Environ. Forensics, 6(3), pp. 273–281. [CrossRef]
Kimes, N. E. , Callaghan, A. V. , Aktas, D. F. , Smith, W. L. , Sunner, J. , Golding, B. , Drozdowska, M. , Hazen, T. C. , Suflita, J. M. , and Morris, P. J. , 2013, “Metagenomic Analysis and Metabolite Profiling of Deep–Sea Sediments From the Gulf of Mexico Following the Deepwater Horizon Oil Spill,” Front. Microbiol., 4(50), pp. 1–17. [PubMed]
Hayworth, J. S. , Prabakhar Clement, T. , John, G. F. , and Yin, F. , 2015, “Fate of Deepwater Horizon Oil in Alabama's Beach System: Understanding Physical Evolution Processes Based on Observational Data,” Mar. Pollut. Bull., 90(1–2), pp. 95–105. [CrossRef] [PubMed]
Blumer, M. , Ehrhardt, M. , and Jones, J. H. , 1973, “The Environmental Fate of Stranded Crude Oil,” Deep Sea Res. Oceanogr. Abstr., 20(3), pp. 239–259. [CrossRef]
Peterson, C. H. , Rice, S. D. , Short, J. W. , Esler, D. , Bodkin, J. L. , Ballachey, B. E. , and Irons, D. B. , 2003, “Long-Term Ecosystem Response to the Exxon Valdez Oil Spill,” Science, 302(5653), pp. 2082–2086. [CrossRef] [PubMed]
Zhanfei, L. , Jiqing, L. , Qingzhi, Z. , and Wei, W. , 2012, “The Weathering of Oil After the Deepwater Horizon Oil Spill: Insights From the Chemical Composition of the Oil From the Sea Surface, Salt Marshes and Sediments,” Environ. Res. Lett., 7(3), p. 035302. [CrossRef]
Venosa, A. D. , and Holder, E. L. , 2013, “Determining the Dispersibility of South Louisiana Crude Oil by Eight Oil Dispersant Products Listed on the NCP Product Schedule,” Mar. Pollut. Bull., 66(1–2), pp. 73–77. [CrossRef] [PubMed]
Riehm, D. A. , and McCormick, A. V. , 2014, “The Role of Dispersants' Dynamic Interfacial Tension in Effective Crude Oil Spill Dispersion,” Mar. Pollut. Bull., 84(1–2), pp. 155–163. [CrossRef] [PubMed]
Athas, J. C. , Jun, K. , McCafferty, C. , Owoseni, O. , John, V. T. , and Raghavan, S. R. , 2014, “An Effective Dispersant for Oil Spills Based on Food-Grade Amphiphiles,” Langmuir, 30(31), pp. 9285–9294. [CrossRef] [PubMed]
Clayton, J. R. , Payne, J. R. , Farlow, J. S. , and Sarwar, C. , 1993, Oil Spill Dispersants: Mechanisms of Action and Laboratory Tests, CRC Press, Boca Raton, FL.
Council, N. R. , 2005, Oil Spill Dispersants: Efficacy and Effects, The National Academies Press, Washington, DC.
Rodd, A. L. , Creighton, M. A. , Vaslet, C. A. , Rangel-Mendez, J. R. , Hurt, R. H. , and Kane, A. B. , 2014, “Effects of Surface-Engineered Nanoparticle-Based Dispersants for Marine Oil Spills on the Model Organism Artemia Franciscana,” Environ. Sci. Technol., 48(11), pp. 6419–6427. [CrossRef] [PubMed]
Kujawinski, E. B. , Kido Soule, M. C. , Valentine, D. L. , Boysen, A. K. , Longnecker, K. , and Redmond, M. C. , 2011, “Fate of Dispersants Associated With the Deepwater Horizon Oil Spill,” Environ. Sci. Technol., 45(4), pp. 1298–1306. [CrossRef] [PubMed]
Hemmer, M. J. , Barron, M. G. , and Greene, R. M. , 2011, “Comparative Toxicity of Eight Oil Dispersants, Louisiana Sweet Crude Oil (LSC), and Chemically Dispersed LSC to Two Aquatic Test Species,” Environ. Toxicol. Chem., 30(10), pp. 2244–2252. [CrossRef] [PubMed]
Etkin, D. S. , 1999, “Estimating Cleanup Costs for Oil Spills,” Int. Oil Spill Conf. Proc., 1999(1), pp. 35–39. [CrossRef]
Bai, G. , Brusseau, M. L. , and Miller, R. M. , 1997, “Biosurfactant-Enhanced Removal of Residual Hydrocarbon From Soil,” J. Contam. Hydrol., 25(1–2), pp. 157–170. [CrossRef]
Urum, K. , and Pekdemir, T. , 2004, “Evaluation of Biosurfactants for Crude Oil Contaminated Soil Washing,” Chemosphere, 57(9), pp. 1139–1150. [CrossRef] [PubMed]
Urum, K. , Grigson, S. , Pekdemir, T. , and McMenamy, S. , 2006, “A Comparison of the Efficiency of Different Surfactants for Removal of Crude Oil From Contaminated Soils,” Chemosphere, 62(9), pp. 1403–1410. [CrossRef] [PubMed]
Mulligan, C. N. , 2009, “Recent Advances in the Environmental Applications of Biosurfactants,” Curr. Opin. Colloid Interface Sci., 14(5), pp. 372–378. [CrossRef]
Zhu, P. , and Papadopoulos, K. D. , 2012, “Visualization and Quantification of Two-Phase Flow in Transparent Miniature Packed Beds,” Phys. Rev. E, 86(4 Pt 2), pp. 046313-1–046313-6.
Zhu, P. , Wang, Q. , Jaimes-Lizcano, Y. A. , and Papadopoulos, K. , 2014, Packed-Bed Capillary Microscopy on BP-Oil-Spill Oil in Porous Media, Wiley, Hoboken, NJ.
Duan, Y. , Deshiikan, S. R. , and Papadopoulos, K. D. , 2013, “Video Microscopic High-Temperature Measurement of Surface Tension,” J. Colloid Interface Sci., 395, pp. 249–255. [CrossRef] [PubMed]
Lenormand, R. , 1990, “Liquids in Porous Media,” J. Phys.: Condens. Matter, 2(S), pp. SA79–SA88. [CrossRef]
Pucci, A. , Barsocchi, C. , Rausa, R. , D'Elia, L. , and Ciardelli, F. , 2005, “Alder Ene Functionalization of Polyisobutene Oligomer and Styrene-Butadiene-Styrene Triblock Copolymer,” Polymers, 46(5), pp. 1497–1505. [CrossRef]
Buckley, J. S. , Liu, Y. , and Monsterleet, S. , 1998, “Mechanisms of Wetting Alteration by Crude Oils,” SPE J., 3(1), pp. 54–61. [CrossRef]
Morrow, N. R. , Lim, H. T. , and Ward, J. S. , 1986, “Effect of Crude-Oil-Induced Wettability Changes on Oil Recovery,” SPE Form. Eval., 1(1), pp. 89–103. [CrossRef]
Yamabe, H. , Tsuji, T. , Liang, Y. , and Matsuoka, T. , 2014, “Lattice Boltzmann Simulations of Supercritical CO2–Water Drainage Displacement in Porous Media: CO2 Saturation and Displacement Mechanism,” Environ. Sci. Technol., 49(1), pp. 537–543. https://pubs.acs.org/doi/abs/10.1021/es504510y [PubMed]
Han, D. , Yang, C. , Zhang, Z. , Lou, Z. , and Chang, Y. , 1999, “Recent Development of Enhanced Oil Recovery in China,” J. Pet. Sci. Eng., 22(1), pp. 181–188. [CrossRef]
Khosravian, H. , Joekar , ‐ Niasar, V. , and Shokri, N. , 2015, “Effects of Flow History on Oil Entrapment in Porous Media: An Experimental Study,” AIChE J, 61(4), pp. 1385–1390. [CrossRef]
Otsu, N. , 1975, “A Threshold Selection Method From Gray-Level Histograms,” Automatica, 11(1), pp. 23–27. https://pdfs.semanticscholar.org/fa29/610048ae3f0ec13810979d0f27ad6971bdbf.pdf
Zack, G. W. , Rogers, W. E. , and Latt, S. A. , 1977, “Automatic Measurement of Sister Chromatid Exchange Frequency,” J. Histochem. Cytochem., 25(7), pp. 741–753. [CrossRef] [PubMed]
Neumann, A. , and Good, R. , 1979, Techniques of Measuring Contact Angles, Springer, Boston, MA.
Washburn, E. W. , 1921, “The Dynamics of Capillary Flow,” Phys. Rev., 17(3), p. 273. [CrossRef]
Taber, J. J. , 1981, Research on Enhanced Oil Recovery: Past, Present and Future, Springer, Boston, MA.
Shah, D. , 1981, “Fundamental Aspects of Surfactant-Polymer Flooding Process,” Third European Symposium on Enhanced Oil Recovery, Bournemouth, UK, Sept. 21–23, Paper No. Code 468.
Fayers, F. J. , 1981, Enhanced Oil Recovery: Proceedings of the Third European Symposium on Enhanced Oil Recovery, Elsevier Scientific Publishing Company, Bournemouth, UK.
Hayashi, S. , and Ikeda, S. , 1980, “Micelle Size and Shape of Sodium Dodecyl Sulfate in Concentrated Sodium Chloride Solutions,” J. Phys. Chem., 84(7), pp. 744–751. [CrossRef]
Pecora, R. , 2013, ed., Dynamic Light Scattering: Applications of Photon Correlation Spectroscopy, Plenum Press, New York.
Dong, M. , Ma, S. , and Liu, Q. , 2009, “Enhanced Heavy Oil Recovery Through Interfacial Instability: A Study of Chemical Flooding for Brintnell Heavy Oil,” Fuel, 88(6), pp. 1049–1056. [CrossRef]
El Ela, M. A. , and Sayyouh, H. , 2014, “An Integrated Approach for the Application of the Enhanced Oil Recovery Projects,” J. Pet. Sci. Res., 3(4), pp. 176–188.


Grahic Jump Location
Fig. 1

Drainage (left) and imbibition (right) two-phase flow in a miniature packed bed

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Fig. 2

“Alder-ene” type synthesis of PIBSA

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Fig. 3

General chemical structure of different PIBSA derivatives

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Fig. 4

Schematic of the flow experiment showing the packed bed (not drawn to scale)

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Fig. 5

Drainage flow patterns for water/crude, water/crude (1 wt % span 80), and water/crude (1 wt % ES) systems at 0.1 and 1.0 μL/min

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Fig. 6

(a) Clean cryolite, (b) water/crude, (c) water/crude (with 1 wt % span 80), and (d) water/crude (with 1 wt % ES) systems after instant imbibition tests at 1.0 μL/min

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Fig. 7

8-bit intensity grayscale stepped pattern

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Fig. 8

Cropped microscopic images of (a) clean cryolite, (b) water/crude, (c) water/crude (with 1 wt % span 80), and (d) water/crude (with 1 wt % ES) systems after instant imbibition tests at 1.0 μL/min

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Fig. 9

Histogram of cropped microscopic images for (a) clean cryolite, (b) water/crude, (c) water/crude (1 wt % span 80), and (d) water/crude (1 wt % ES) systems after instant imbibition tests at 1.0 μL/min

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Fig. 10

Cropped binary microscopic images (×4) of for (a) clean cryolite, (b) water/crude, (c) water/crude (1 wt % span 80), and (d) water/crude (1 wt % ES) systems after instant imbibition tests at 1.0 μL/min

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Fig. 11

Microscopic pictures (×20) of two cryolite packed beds after instant imbibition with crude oil containing span 80 1 wt % (left) and crude oil containing ES 1 wt % (right)

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Fig. 12

Lognormal size distribution of (a) 20 nm Polystyrene latex, (b) SDS alone, and (c) SDS:ES (100:1)



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