Abstract
Mitigating the massive emissions of greenhouse gases is one of the main measures taken to resolve the current growing climate problems. The electrochemical reduction of carbon dioxide to economically valuable chemical fuels has attracted the intensive attention of scholars. This review provides an overview of the application of conductive diamond in electrocatalytic reduction and outlines the improvement of electrochemical properties by employing metal particles to modify the surface. Meanwhile, the carbon-based electrode materials represented by glassy carbon and diamond-like carbon also have broad research value. Emphasis is placed on the electrochemical properties of boron-doped, transition metal modification, and co-doped diamond film electrodes with appropriate extensions. The carbon-chain compounds produced by the reduction reaction are also briefly described, mainly using formic acid and ethanol as examples, and focusing on the switchable selectivity of the multi-carbon products. In addition, the development directions of electrochemical reduction technology are prospected.
Issue Section:
Review Article
References
1.
Cao
, L.
, and Caldeira
, K.
, 2008
, “Atmospheric CO2 Stabilization and Ocean Acidification
,” Geophys. Res. Lett.
, 35
(19
), p. 19609
. 2.
Zhang
, S.
, Jiang
, J.
, Wang
, H.
, Li
, F.
, Hua
, T.
, and Wang
, W.
, 2021
, “A Review of Microbial Electrosynthesis Applied to Carbon Dioxide Capture and Conversion: The Basic Principles, Electrode Materials, and Bioproducts
,” J. CO2 Util.
, 51
(20
), p. 101640
. 3.
Nguyen
, T. N.
, and Dinh
, C.-T.
, 2020
, “Gas Diffusion Electrode Design for Electrochemical Carbon Dioxide Reduction
,” Chem. Soc. Rev.
, 49
(21
), pp. 7488
–7504
. 4.
Kibria
, M. G.
, Edwards
, J. P.
, Gabardo
, C. M.
, Cao-Thang
, D.
, Seifitokaldani
, A.
, Sinton
, D.
, and Sargent
, E. H.
, 2019
, “Electrochemical CO2 Reduction Into Chemical Feedstocks: From Mechanistic Electrocatalysis Models to System Design
,” Adv. Mater.
, 31
(31
), p. 1807166
. 5.
Rabiee
, H.
, Ge
, L.
, Zhang
, X.
, Hu
, S.
, Li
, M.
, and Yuan
, Z.
, 2021
, “Gas Diffusion Electrodes (GDEs) for Electrochemical Reduction of Carbon Dioxide, Carbon Monoxide, and Dinitrogen to Value-Added Products: A Review
,” Energy Environ. Sci.
, 14
(4
), pp. 1959
–2008
. 6.
Wu
, J.
, Huang
, Y.
, Ye
, W.
, and Li
, Y.
, 2017
, “CO2 Reduction: From the Electrochemical to Photochemical Approach
,” Adv. Sci.
, 4
(11
), p. 1700194
. 7.
Bai
, X.-F.
, Chen
, W.
, Wang
, B.-Y.
, Feng
, G.-H.
, Wei
, W.
, Jiao
, Z.
, and Sun
, Y.-H.
, 2017
, “Recent Progress on Electrochemical Reduction of Carbon Dioxide
,” Acta Phys. Chim. Sin.
, 33
(12
), pp. 2388
–2403
. 8.
Luo
, Y.
, Zhang
, K.
, Li
, Y.
, and Wang
, Y.
, 2021
, “Valorizing Carbon Dioxide Via Electrochemical Reduction on Gas-Diffusion Electrodes
,” Infomat
, 3
(12
), pp. 1313
–1332
. 9.
Nakabayashi
, Y.
, Hirano
, Y.
, Sakurai
, Y.
, Okazaki
, A.
, Kuriyama
, H.
, Roy
, N.
, Suzuki
, N.
, et al, 2018
, “Positive Shift in the Potential of Photo-Electrochemical CO2 Reduction to CO on Ag-Loaded Boron-Doped Diamond Electrode by an Electrochemical Pre-Treatment
,” J. Appl. Electrochem.
, 48
(1
), pp. 61
–73
. 10.
Sastre
, F.
, Puga
, A. V.
, Liu
, L.
, Corma
, A.
, and Garcia
, H.
, 2014
, “Complete Photocatalytic Reduction of CO2 to Methane by h-2 Under Solar Light Irradiation
,” J. Am. Chem. Soc.
, 136
(19
), pp. 6798
–6801
. 11.
Pander
, J. E.
, Ren
, D.
, Huang
, Y.
, Loo
, N. W. X.
, Hong
, S. H. L.
, and Yeo
, B. S.
, 2018
, “Understanding the Heterogeneous Electrocatalytic Reduction of Carbon Dioxide on Oxide-Derived Catalysts
,” ChemElectroChem
, 5
(2
), pp. 219
–237
. 12.
Chan
, K.
, Tsai
, C.
, Hansen
, H. A.
, and Norskov
, J. K.
, 2014
, “Molybdenum Sulfides and Selenides as Possible Electrocatalysts for CO2 Reduction
,” ChemCatChem
, 6
(7
), pp. 1899
–1905
. 13.
Garg
, S.
, Li
, M.
, Weber
, A. Z.
, Ge
, L.
, Li
, L.
, Rudolph
, V.
, Wang
, G.
, and Rufford
, T. E.
, 2020
, “Advances and Challenges in Electrochemical CO2 Reduction Processes: An Engineering and Design Perspective Looking Beyond New Catalyst Materials
,” J. Mater. Chem. A
, 8
(4
), pp. 1511
–1544
. 14.
Zhu
, D. D.
, Liu
, J. L.
, and Qiao
, S. Z.
, 2016
, “Recent Advances in Inorganic Heterogeneous Electrocatalysts for Reduction of Carbon Dioxide
,” Adv. Mater.
, 28
(18
), pp. 3423
–3452
. 15.
Fang
, Y.
, and Flake
, J. C.
, 2017
, “Electrochemical Reduction of CO2 at Functionalized Au Electrodes
,” J. Am. Chem. Soc.
, 139
(9
), pp. 3399
–3405
. 16.
Sangiorgi
, N.
, Tuci
, G.
, Sanson
, A.
, Peruzzini
, M.
, and Giambastiani
, G.
, 2019
, “Metal-Free Carbon-Based Materials for Electrocatalytic and Photo-Electrocatalytic CO2 Reduction
,” Rend. Lincei Sci. Fis. Nat.
, 30
(3
), pp. 497
–513
. 17.
Liu
, Z.
, Wang
, Z.
, Qing
, S.
, Xue
, N.
, Jia
, S.
, Zhang
, L.
, Li
, L.
, Li
, N.
, Shi
, L.
, and Chen
, J.
, 2018
, “Improving Methane Selectivity of Photo-Induced CO2 Reduction on Carbon Dots Through Modification of Nitrogen-Containing Groups and Graphitization
,” Appl. Catal. B
, 232
, pp. 86
–92
. 18.
Akhundi
, A.
, Habibi-Yangjeh
, A.
, Abitorabi
, M.
, and Pouran
, S. R.
, 2019
, “Review on Photocatalytic Conversion of Carbon Dioxide to Value-Added Compounds and Renewable Fuels by Graphitic Carbon Nitride-Based Photocatalysts
,” Catal. Rev. Sci. Eng.
, 61
(4
), pp. 595
–628
. 19.
Yang
, N.
, Yu
, S.
, Macpherson
, J. V.
, Einaga
, Y.
, Zhao
, H.
, Zhao
, G.
, Swain
, G. M.
, and Jiang
, X.
, 2019
, “Conductive Diamond: Synthesis, Properties, and Electrochemical Applications
,” Chem. Soc. Rev.
, 48
(1
), pp. 157
–204
. 20.
Yang
, N.
, Foord
, J. S.
, and Jiang
, X.
, 2016
, “Diamond Electrochemistry at the Nanoscale: A Review
,” Carbon
, 99
, pp. 90
–110
. 21.
Luo
, D.
, Nakata
, K.
, Fujishima
, A.
, and Liu
, S.
, 2017
, “Photochemistry and Photo-Electrochemistry on Synthetic Semiconducting Diamond
,” J. Photochem. Photobiol. C
, 31
, pp. 139
–152
. 22.
Pleskov
, Y. V.
, Krotova
, M. D.
, Elkin
, V. V.
, Varnin
, V. P.
, and Teremetskaya
, I. G.
, 2013
, “Characterization of CVD Diamond Thin Film Electrodes in Terms of Their Semiconductivity
,” Electrocatalysis
, 4
(4
), pp. 241
–244
. 23.
Eguiluz
, K. I. B.
, Peralta-Hernández
, J. M.
, Hernández-Ramírez
, A.
, Guzmán-Mar
, J. L.
, Hinojosa-Reyes
, L.
, Martínez-Huitle
, C. A.
, and Salazar-Banda
, G. R.
, 2012
, “The Use of Diamond for Energy Conversion System Applications: A Review
,” Int. J. Electrochem.
, 2012
, pp. 1
–20
. 24.
Rodrigo
, M. A.
, Canizares
, P.
, Sanchez-Carretero
, A.
, and Saez
, C.
, 2010
, “Use of Conductive-Diamond Electrochemical Oxidation for Wastewater Treatment
,” Catal. Today
, 151
(1–2
), pp. 173
–177
. 25.
Medina-Sanchez
, M.
, Mayorga-Martinez
, C. C.
, Watanabe
, T.
, Ivandini
, T. A.
, Honda
, Y.
, Pino
, F.
, Nakata
, K.
, Fujishima
, A.
, Einaga
, Y.
, and Merkoci
, A.
, 2016
, “Microfluidic Platform for Environmental Contaminants Sensing and Degradation Based on Boron-Doped Diamond Electrodes
,” Biosens. Bioelectron.
, 75
, pp. 365
–374
. 26.
Fernandes da Costa
, P. R.
, dos Santos
, E. V.
, Peralta-Hernandez
, J. M.
, Salazar-Banda
, G. R.
, da Silva
, D. R.
, and Martinez-Huitle
, C. A.
, 2015
, “Modified Diamond Electrodes for Electrochemical Systems for Energy Conversion and Storage
,” Top. Appl. Phys.
, 121
, pp. 205
–235
. 27.
Yu
, S.
, Yang
, N.
, Liu
, S.
, and Jiang
, X.
, 2021
, “Electrochemical and Photochemical CO2 Reduction Using Diamond
,” Carbon
, 175
(4
), pp. 440
–453
. 28.
Zalieckas
, J.
, Pobedinskas
, P.
, Greve
, M. M.
, Eikehaug
, K.
, Haenen
, K.
, and Holst
, B.
, 2021
, “Large Area Microwave Plasma CVD of Diamond Using Composite Right/Left-Handed Materials
,” Diamond Relat. Mater.
, 116
(7
), p. 108394
. 29.
Kim
, H.-Y.
, Kim
, D.-S.
, Kim
, K.-S.
, and Hwang
, N.-M.
, 2020
, “Various Allotropes of Diamond Nanoparticles Generated in the Gas Phase During Hot Filament Chemical Vapor Deposition
,” Nanomaterials
, 10
(12
), p. 2504
. 30.
Shen
, B.
, Sun
, F.
, and Yang
, G.
, 2010
, “Study on the Friction Behavior of HFCVD Diamond Films on Silicon Nitride Substrates
,” Adv. Mater. Res.
, 135
, pp. 143
–148
. www.scientific.net/amr.135.14331.
Hatada
, R.
, Flege
, S.
, Ensinger
, W.
, and Baba
, K.
, 2020
, “Deposition of Diamond-Like Carbon Films on Insulating Substrates by Plasma Source Ion Implantation
,” Surf. Coat. Technol.
, 385
, p. 125426
. 32.
Sumikura
, H.
, Hirama
, K.
, Nishiguchi
, K.
, Shinya
, A.
, and Notomi
, M.
, 2020
, “Highly Nitrogen-Vacancy Doped Diamond Nanostructures Fabricated by Ion Implantation and Optimum Annealing
,” APL Mater.
, 8
(3
), p. 031113
. 33.
Liu
, J. W.
, Teraji
, T.
, Da
, B.
, Ohsato
, H.
, and Koide
, Y.
, 2020
, “Effect of Annealing Temperature on Performances of Boron-Doped Diamond Metal-Semiconductor Field-Effect Transistors
,” IEEE Trans. Electron. Dev.
, 67
(4
), pp. 1680
–1685
. 34.
Hu
, H.
, Hu
, X. J.
, Bai
, B. W.
, and Chen
, X. H.
, 2012
, “Effects of Annealing Time on the Microstructural and Electrochemical Properties of b-Doped Nanocrystalline Diamond Films
,” Acta Phys. Sin.
, 61
(14
), p. 148101
. 35.
Fu
, X.
, Xu
, Z.
, He
, Z.
, Hartmaier
, A.
, and Fang
, F.
, 2019
, “Molecular Dynamics Simulation of Silicon Ion Implantation Into Diamond and Subsequent Annealing
,” Nucl. Instrum. Methods B
, 450
, pp. 51
–55
. 36.
Li
, X.
, Ke
, P.
, and Wang
, A.
, 2015
, “Ab Initio Molecular Dynamics Simulation on Stress Reduction Mechanism of Ti-Doped Diamond-Like Carbon Films
,” Thin Solid Films
, 584
, pp. 204
–207
. 37.
Lehtinen
, O.
, Naydenov
, B.
, Boerner
, P.
, Melentjevic
, K.
, Mueller
, C.
, McGuinness
, L. P.
, Pezzagna
, S.
, Meijer
, J.
, Kaiser
, U.
, and Jelezko
, F.
, 2016
, “Molecular Dynamics Simulations of Shallow Nitrogen and Silicon Implantation Into Diamond
,” Phys. Rev. B
, 93
(3
), p. 035202
. 38.
Einaga
, Y.
, 2010
, “Diamond Electrodes for Electrochemical Analysis
,” J. Appl. Electrochem.
, 40
(10
), pp. 1807
–1816
. 39.
Jiwanti
, P.
, Natsui
, K.
, Nakata
, K.
, and Einaga
, Y.
, 2016
, “Selective Production of Methanol by the Electrochemical Reduction of CO2 on Boron-Doped Diamond Electrodes in Aqueous Ammonia Solution
,” RSC Adv.
, 6
(104
), pp. 102214
–102217
. 40.
Luo
, D.
, Liu
, S.
, Nakata
, K.
, and Fujishima
, A.
, 2019
, “Electrochemical Reduction of CO2 and Degradation of khp on Boron-Doped Diamond Electrodes in a Simultaneous and Enhanced Process
,” Chin. Chem. Lett.
, 30
(2
), pp. 509
–512
. 41.
Tomisaki
, M.
, Kasahara
, S.
, Natsui
, K.
, Ikemiya
, N.
, and Einaga
, Y.
, 2019
, “Switchable Product Selectivity in the Electrochemical Reduction of Carbon Dioxide Using Boron-Doped Diamond Electrodes
,” J. Am. Chem. Soc.
, 141
(18
), pp. 7414
–7420
. 42.
Peng
, Z.
, Xu
, J.
, Kurihara
, K.
, Tomisaki
, M.
, and Einaga
, Y.
, 2021
, “Electrochemical CO2 Reduction on Sub-Microcrystalline Boron-Doped Diamond Electrodes
,” Diamond Relat. Mater.
, 120
, p. 108608
. 43.
Roy
, N.
, Suzuki
, N.
, Nakabayashi
, Y.
, Hirano
, Y.
, Ikari
, H.
, Katsumata
, K.-I.
, Nakata
, K.
, Fujishima
, A.
, and Terashima
, C.
, 2018
, “Facile Deposition of Cu-Snox Hybrid Nanostructures on Lightly Boron-Doped Diamond Electrodes for CO2 Reduction
,” ChemElectroChem
, 5
(18
), pp. 2542
–2550
. 44.
Luo
, D.
, Ma
, D.
, Liu
, S.
, Nakata
, K.
, Fujishima
, A.
, and Wu
, L.
, 2022
, “Electrochemical Reduction of CO2 on Fluorine-Modified Boron-Doped Diamond Electrode
,” Diamond Relat. Mater.
, 121
, p. 108753
. 45.
Xu
, J.
, and Einaga
, Y.
, 2020
, “Effect of sp(2) Species in a Boron-Doped Diamond Electrode on the Electrochemical Reduction of CO2
,” Electrochem. Commun.
, 115
, p. 106731
. 46.
Liu
, Y.
, Chen
, S.
, Quan
, X.
, and Yu
, H.
, 2015
, “Efficient Electrochemical Reduction of Carbon Dioxide to Acetate on Nitrogen-Doped Nanodiamond
,” J. Am. Chem. Soc.
, 137
(36
), pp. 11631
–11636
. 47.
Wang
, H.
, Tzeng
, Y.-K.
, Ji
, Y.
, Li
, Y.
, Li
, J.
, Zheng
, X.
, Yang
, A.
, et al, 2020
, “Synergistic Enhancement of Electrocatalytic CO2 Reduction to C-2 Oxygenates at Nitrogen-Doped Nanodiamonds/Cu Interface
,” Nat. Nanotechnol.
, 15
(2
), pp. 131
–137
. 48.
Naragino
, H.
, Saitoh
, Y.
, and Honda
, K.
, 2022
, “Electrochemical Reduction of Carbon Dioxide in an Aqueous Solution Using Phosphorus-Doped Polycrystalline Diamond Electrodes
,” Electrochem. Commun.
, 134
(6
), p. 107164
. 49.
Yang
, B.
, Peng
, X.
, Huang
, C.
, Zhao
, Y.
, Chen
, X.
, Zhang
, G.
, and Fu
, T.
, 2019
, “Toughening and Maintaining Strength of Diamond With Substitutional Doping Boron and Nitrogen
,” J. Alloys Compd.
, 805
, pp. 1090
–1095
. 50.
Souza
, F. L.
, Lopes
, O. F.
, Santos
, E. V.
, and Ribeiro
, C.
, 2022
, “Promoting CO2 Electroreduction on Boron-Doped Diamond Electrodes: Challenges and Trends
,” Curr. Opin. Electrochem.
, 32
, p. 100890
. 51.
Freitas
, J. M.
, TdC
, O.
, Abarza Munoz
, R. A.
, and Richter
, E. M.
, 2019
, “Boron Doped Diamond Electrodes in Flow-Based Systems
,” Front. Chem.
, 7
, p. 190
. 52.
Einaga
, Y.
, 2022
, “Application of Boron-Doped Diamond Electrodes: Focusing on the Electrochemical Reduction of Carbon Dioxide
,” Electrochemistry
, 90
(10
), pp. 101002
–101002
. 53.
Yu
, S.
, Yang
, N.
, Zhuang
, H.
, Meyer
, J.
, Mandal
, S.
, Williams
, O. A.
, Lilge
, I.
, Schoenherr
, H.
, and Jiang
, X.
, 2015
, “Electrochemical Supercapacitors From Diamond
,” J. Phys. Chem. C
, 119
(33
), pp. 18918
–18926
. 54.
Zhou
, M.
, Zhai
, Z.
, Liu
, L.
, Zhang
, C.
, Yuan
, Z.
, Lu
, Z.
, Chen
, B.
, et al, 2021
, “Controllable Synthesized Diamond/CNWS Film as a Novel Nanocarbon Electrode With Wide Potential Window and Enhanced s/b Ratio for Electrochemical Sensing
,” Appl. Surf. Sci.
, 551
, p. 149418
. 55.
Manciu
, F. S.
, Manciu
, M.
, Durrer
, W. G.
, Salazar
, J. G.
, Lee
, K. H.
, and Bennet
, K. E.
, 2014
, “A Drude Model Analysis of Conductivity and Free Carriers in Boron-Doped Diamond Films and Investigations of Their Internal Stress and Strain
,” J. Mater. Sci.
, 49
(16
), pp. 5782
–5789
. 56.
Du
, J.
, Fiorani
, A.
, Inagaki
, T.
, Otake
, A.
, Murata
, M.
, Hatanaka
, M.
, and Einaga
, Y.
, 2022
, “A New Pathway for CO2 Reduction Relying on the Self-Activation Mechanism of Boron-Doped Diamond Cathode
,” JACS Au
, 2
(6
), pp. 1375
–1382
. 57.
Otake
, A.
, Du
, J.
, and Einaga
, Y.
, 2022
, “Activation of Boron-Doped Diamond Electrodes for Electrochemical CO2 Reduction in a Halogen-Free Electrolyte
,” ACS Sustain. Chem. Eng.
, 10
(44
), pp. 14445
–14450
. 58.
Kageura
, T.
, Sasama
, Y.
, Shinei
, C.
, Teraji
, T.
, Yamada
, K.
, Onoda
, S.
, and Takahide
, Y.
, 2022
, “Charge Stability of Shallow Single Nitrogen-Vacancy Centers in Lightly Boron-Doped Diamond
,” Carbon
, 192
, pp. 473
–481
. 59.
Wang
, Z. L.
, Lu
, C.
, Li
, J. J.
, and Gu
, C. Z.
, 2009
, “Effect of Gas Composition on the Growth and Electrical Properties of Boron-Doped Diamond Films
,” Diamond Relat. Mater.
, 18
(2–3
), pp. 132
–135
. 60.
Xu
, J.
, Natsui
, K.
, Naoi
, S.
, Nakata
, K.
, and Einaga
, Y.
, 2018
, “Effect of Doping Level on the Electrochemical Reduction of CO2 on Boron-Doped Diamond Electrodes
,” Diamond Relat. Mater.
, 86
, pp. 167
–172
. 61.
Wood
, G. F.
, Zvoriste-Walters
, C. E.
, Munday
, M. G.
, Newton
, M. E.
, Shkirskiy
, V.
, Unwin
, P. R.
, and Macpherson
, J. V.
, 2021
, “High Pressure High Temperature Synthesis of Highly Boron Doped Diamond Microparticles and Porous Electrodes for Electrochemical Applications
,” Carbon
, 171
, pp. 845
–856
. 62.
Watanabe
, T.
, Yoshioka
, S.
, Yamamoto
, T.
, Sepehri-Amin
, H.
, Ohkubo
, T.
, Matsumura
, S.
, and Einaga
, Y.
, 2018
, “The Local Structure in Heavily Boron-Doped Diamond and the Effect This Has on Its Electrochemical Properties
,” Carbon
, 137
, pp. 333
–342
. 63.
Bhattacharyya
, S.
, Auciello
, O.
, Birrell
, J.
, Carlisle
, J.
, Curtiss
, L. A.
, Goyette
, A.
, Gruen
, D.
, et al, 2001
, “Synthesis and Characterization of Highly-Conducting Nitrogen-Doped Ultrananocrystalline Diamond Films
,” Appl. Phys. Lett.
, 79
(10
), pp. 1441
–1443
. 64.
Rakha
, S. A.
, Xintai
, Z.
, Zhu
, D.
, and Guojun
, Y.
, 2010
, “Effects of n-2 Addition on Nanocrystalline Diamond Films by HFCVD in Ar/Ch4 Gas Mixture
,” Curr. Appl. Phys.
, 10
(1
), pp. 171
–175
. 65.
Ayestarán Latorre
, C.
, Ewen
, J. P.
, Dini
, D.
, and Righi
, M. C.
, 2021
, “Ab Initio Insights Into the Interaction Mechanisms Between Boron, Nitrogen and Oxygen Doped Diamond Surfaces and Water Molecules
,” Carbon
, 171
, pp. 575
–584
. 66.
Cordero
, B.
, Gómez
, V.
, Platero-Prats
, A. E.
, Revés
, M.
, Echeverría
, J.
, Cremades
, E.
, Barragán
, F.
, and Alvarez
, S.
, 2008
, “Covalent Radii Revisited
,” Dalton Trans.
, 21
(21
), pp. 2832
–2838
. 67.
Liu
, T.
, and Raabe
, D.
, 2009
, “Influence of Nitrogen Doping on Growth Rate and Texture Evolution of Chemical Vapor Deposition Diamond Films
,” Appl. Phys. Lett.
, 94
(2
), p. 021119
. 68.
Müller-Sebert
, W.
, Wörner
, E.
, Fuchs
, F.
, Wild
, C.
, and Koidl
, P.
, 1996
, “Nitrogen Induced Increase of Growth Rate in Chemical Vapor Deposition of Diamond
,” Appl. Phys. Lett.
, 68
(6
), pp. 759
–760
. 69.
Locher
, R.
, Wild
, C.
, Herres
, N.
, Behr
, D.
, and Koidl
, P.
, 1994
, “Nitrogen Stabilized 〈100〉 Texture in Chemical Vapor Deposited Diamond Films
,” Appl. Phys. Lett.
, 65
(1
), pp. 34
–36
. 70.
Matsumoto
, T.
, Mukose
, T.
, Makino
, T.
, Takeuchi
, D.
, Yamasaki
, S.
, Inokuma
, T.
, and Tokuda
, N.
, 2017
, “Diamond Schottky-Pn Diode Using Lightly Nitrogen-Doped Layer
,” Diamond Relat. Mater.
, 75
, pp. 152
–154
. 71.
Pleskov
, Y. V.
, Krotova
, M. D.
, Elkin
, V. V.
, Ralchenko
, V. G.
, Saveliev
, A. V.
, Pimenov
, S. M.
, and Lim
, P. Y.
, 2007
, “N-Type Nitrogenated Nanocrystalline Diamond Thin-Film Electrodes: The Effect of the Nitrogenation on Electrochemical Properties
,” Electrochim. Acta
, 52
(17
), pp. 5470
–5478
. 72.
Hu
, Q.
, Han
, Z.
, Wang
, X.
, Li
, G.
, Wang
, Z.
, Huang
, X.
, Yang
, H.
, et al, 2020
, “Facile Synthesis of Sub-Nanometric Copper Clusters by Double Confinement Enables Selective Reduction of Carbon Dioxide to Methane
,” Angew. Chem. Int. Ed.
, 59
(43
), pp. 19054
–19059
. 73.
Malapit
, C. A.
, Prater
, M. B.
, Cabrera-Pardo
, J. R.
, Li
, M.
, Pham
, T. D.
, McFadden
, T. P.
, Blank
, S.
, and Minteer
, S. D.
, 2022
, “Advances on the Merger of Electrochemistry and Transition Metal Catalysis for Organic Synthesis
,” Chem. Rev.
, 122
(3
), pp. 3180
–3218
. 74.
Toghill
, K. E.
, and Compton
, R. G.
, 2010
, “Metal Nanoparticle Modified Boron Doped Diamond Electrodes for Use in Electroanalysis
,” Electroanalysis
, 22
(17–18
), pp. 1947
–1956
. 75.
Jones
, S. E. W.
, and Compton
, R. G.
, 2008
, “Fabrication and Applications of Nanoparticle-Modified Electrodes in Stripping Analysis
,” Curr. Anal. Chem.
, 4
(3
), pp. 177
–182
. 76.
Campbell
, F. W.
, and Compton
, R. G.
, 2010
, “The Use of Nanoparticles in Electroanalysis: An Updated Review
,” Anal. Bioanal. Chem.
, 396
(1
), pp. 241
–259
. 77.
Riedel
, M.
, Mantel
, B.
, Ristein
, J.
, and Ley
, L.
, 2000
, “Origin of Surface Conductivity in Diamond
,” Phys. Rev. Lett.
, 85
(16
), pp. 3472
–3475
. 78.
Zhu
, Q.
, Sun
, X.
, Yang
, D.
, Ma
, J.
, Kang
, X.
, Zheng
, L.
, Zhang
, J.
, Wu
, Z.
, and Han
, B.
, 2019
, “Carbon Dioxide Electroreduction to c-2 Products Over Copper-Cuprous Oxide Derived From Electrosynthesized Copper Complex
,” Nat. Commun.
, 10
(1
), p. 3851
. 79.
Nakabayashi
, Y.
, Hirano
, Y.
, Sakurai
, Y.
, Okazaki
, A.
, Kuriyama
, H.
, Roy
, N.
, Suzuki
, N.
, et al, 2018
, “Positive Shift in the Potential of Photo-Electrochemical CO2 Reduction to CO on Ag-Loaded Boron-Doped Diamond Electrode by an Electrochemical Pre-Treatment
,” J. Appl. Electrochem.
, 48
(1
), pp. 61
–73
. 80.
Romero Cuellar
, N. S.
, Wiesner-Fleischer
, K.
, Hinrichsen
, O.
, and Fleischer
, M.
, 2018
, “Electrochemical Reduction of CO2 in Water-Based Electrolytes KHCO3 and K2SO4 Using Boron Doped Diamond Electrodes
,” ChemistrySelect
, 3
(13
), pp. 3591
–3595
. 81.
Jiwanti
, P. K.
, Ichzan
, A. M.
, Dewandaru
, R. K. P.
, Atriardi
, S. R.
, Einaga
, Y.
, and Ivandini
, T. A.
, 2020
, “Improving the CO2 Electrochemical Reduction to Formic Acid Using Iridium-Oxide-Modified Boron-Doped Diamond Electrodes
,” Diamond Relat. Mater.
, 106
, p. 107874
. 82.
Verlato
, E.
, Barison
, S.
, Einaga
, Y.
, Fasolin
, S.
, Musiani
, M.
, Nasi
, L.
, Natsui
, K.
, Paolucci
, F.
, and Valenti
, G.
, 2019
, “CO2 Reduction to Formic Acid at Low Overpotential on bdd Electrodes Modified With Nanostructured CeO2
,” J. Mater. Chem. A
, 7
(30
), pp. 17896
–17905
. 83.
Ivandini
, T. A.
, 2018
, “Electrochemical Conversion of CO2 at Metal-Modified Boron-Doped Diamond Electrodes
,” AIP Conf. Proc.
, 2023
(1
), p. 020102
. 84.
Denala
, D.
, Khalil
, M.
, and Ivandini
, T. A.
, 2019
, “Preparation of Boron Doped Diamond Modified With Cuprous Oxide as Working Electrode for Electroreduction of CO2
,” AIP Conf. Proc.
, 2168
(1
), p. 020057
. 85.
Jiwanti
, P. K.
, and Einaga
, Y.
, 2020
, “Further Study of CO2 Electrochemical Reduction on Palladium Modified bdd Electrode: Influence of Electrolyte
,” Chem. Asian J.
, 15
(6
), pp. 910
–914
. 86.
Jiwanti
, P.
, and Einaga
, Y.
, 2019
, “Electrochemical Reduction of CO2 Using Palladium Modified Boron Doped Diamond Electrodes: Enhancing the Production of CO
,” Phys. Chem. Chem. Phys.
, 21
(28
), pp. 15297
–15301
. 87.
Atriardi
, S. R.
, Dewandaru
, R. K. P.
, Gunlazuardi
, J.
, and Ivandini
, T. A.
, 2019
, “Modification of Boron-Doped Diamond Electrodes With Platinum-Iridium for Carbon Dioxide Electroreduction
,” IOP Conf. Ser.: Mater. Sci. Eng.
, 496
, p. 012040
. 88.
Gunlazuardi
, J.
, and Ivandini
, T. A.
, 2017
, “Preparation of Platinum-Modified Boron-Doped Diamond for Electroreduction of CO2
,” IOP Conf. Ser.: Mater. Sci. Eng.
, 188
(1
), p. 012037
. 89.
Dyachenko
, A. G.
, Tsapyuk
, G. G.
, Gaidai
, S. V.
, Ischenko
, O. V.
, Zakharova
, T. M.
, Il'nitskaya
, G. D.
, and Loginova
, O. B.
, 2020
, “Synthetic Nanodiamonds (SNDs) Containing Bimetallic Ni(Co)-Fe Composites: Preparation, Characterization and Catalytic Performance in the Reaction of Co(2)Methanation
,” Mol. Cryst. Liq. Cryst.
, 701
(1
), pp. 91
–97
. 90.
Jiwanti
, P. K.
, Sultana
, S.
, Wicaksono
, W. P.
, and Einaga
, Y.
, 2021
, “Metal Modified Carbon-Based Electrode for CO2 Electrochemical Reduction: A Review
,” J. Electroanal. Chem.
, 898
, p. 115634
. 91.
Jiwanti
, P. K.
, and Einaga
, Y.
, 2019
, “Electrochemical Reduction of CO2 Using Palladium Modified Boron-Doped Diamond Electrodes: Enhancing the Production of CO
,” Phys. Chem. Chem. Phys.
, 21
(28
), pp. 15297
–15301
. 92.
Yetri
, N. Y.
, Ivandini
, T. A.
, and Gunlazuardi
, J.
, 2017
, “Preparation of Copper Oxide Modified Boron-Doped Diamond Electrodes and Its Preliminary Study for CO2 Reduction
,” IOP Conf. Ser.: Mater. Sci. Eng.
, 188
(1
), p. 012011
. 93.
Roy
, N.
, Shibano
, Y.
, Terashima
, C.
, Katsumata
, K.-I.
, Nakata
, K.
, Kondo
, T.
, Yuasa
, M.
, and Fujishima
, A.
, 2016
, “Ionic-Liquid-Assisted Selective and Controlled Electrochemical CO2 Reduction at Cu-Modified Boron-Doped Diamond Electrode
,” ChemElectroChem
, 3
(7
), pp. 1044
–1047
. 94.
Jakšić
, M. M.
, 1984
, “Electrocatalysis of Hydrogen Evolution in the Light of the Brewer—Engel Theory for Bonding in Metals and Intermetallic Phases
,” Electrochim. Acta
, 29
(11
), pp. 1539
–1550
. 95.
Fu
, X.
, Zhu
, A.
, Chen
, X.
, Zhang
, S.
, Wang
, M.
, and Yuan
, M.
, 2021
, “Stabilization of Cu/Ni Alloy Nanoparticles With Graphdiyne Enabling Efficient CO2 Reduction
,” Chem. Res. Chin. Univ.
, 37
(6
), pp. 1328
–1333
. 96.
Kondo
, T.
, Aoshima
, S.
, Honda
, K.
, Einaga
, Y.
, and Fujishima
, K. T.
, 2007
, “Fabrication of Covalent Sam/Au Nanoparticle/Boron-Doped Diamond Configurations With a Sequential Self-Assembly Method
,” J. Phys. Chem. C
, 111
(34
), pp. 12650
–12657
. 97.
Shah
, U. V.
, Olusanmi
, D.
, Narang
, A. S.
, Hussain
, M. A.
, Gamble
, J. F.
, Tobyn
, M. J.
, and Heng
, J. Y. Y.
, 2014
, “Effect of Crystal Habits on the Surface Energy and Cohesion of Crystalline Powders
,” Int. J. Pharm.
, 472
(1–2
), pp. 140
–147
. 98.
Li
, J.
, Umar Abbas
, S.
, Wang
, H.
, Zhang
, Z.
, and Hu
, W.
, 2021
, “Recent Advances in Interface Engineering for Electrocatalytic CO2 Reduction Reaction
,” Nano-Micro Lett.
, 13
(1
), p. 216
. 99.
Wanninayake
, N.
, Ai
, Q.
, Zhou
, R.
, Hoque
, M. A.
, Herrell
, S.
, Guzman
, M. I.
, Risko
, C.
, and Kim
, D. Y.
, 2020
, “Understanding the Effect of Host Structure of Nitrogen Doped Ultrananocrystalline Diamond Electrode on Electrochemical Carbon Dioxide Reduction
,” Carbon
, 157
, pp. 408
–419
. 100.
Ramírez-Valencia
, L. D.
, Bailón-García
, E.
, Carrasco-Marín
, F.
, and Pérez-Cadenas
, A. F.
, 2021
, “From CO2 to Value-Added Products: A Review About Carbon-Based Materials for Electro-Chemical CO2 Conversion
,” Catalysts
, 11
(3
), p. 351
. 101.
Liu
, Y.
, Quan
, X.
, Yu
, H.
, Zhao
, H.
, Zhang
, Y.
, and Chen
, G.
, 2013
, “Boron and Nitrogen Codoped Nanodiamond as an Efficient Metal-Free Catalyst for Oxygen Reduction Reaction
,” J. Phys. Chem. C
, 117
(29
), pp. 14992
–14998
. 102.
Ma
, X.
, Du
, J.
, Sun
, H.
, Ye
, F.
, Wang
, X.
, Xu
, P.
, Hu
, C.
, Zhang
, L.
, and Liu
, D.
, 2021
, “Boron, Nitrogen Co-Doped Carbon With Abundant Mesopores for Efficient CO2 Electroreduction
,” Appl. Catal. B
, 298
, p. 120543
. 103.
Masood ul Hasan
, I.
, Peng
, L.
, Mao
, J.
, He
, R.
, Wang
, Y.
, Fu
, J.
, Xu
, N.
, and Qiao
, J.
, 2021
, “Carbon-Based Metal-Free Catalysts for Electrochemical CO2 Reduction: Activity, Selectivity, and Stability
,” Carbon Energy
, 3
(1
), pp. 24
–49
. 104.
Guo
, T.
, Yang
, N.
, Yang
, B.
, Schulte
, A.
, Jin
, Q.
, Koch
, U.
, Mandal
, S.
, et al, 2021
, “Electrochemistry of Nitrogen and Boron Bi-Element Incorporated Diamond Films
,” Carbon
, 178
(3
), pp. 19
–25
. 105.
Knittel
, P.
, Buchner
, F.
, Hadzifejzovic
, E.
, Giese
, C.
, Quellmalz
, P.
, Seidel
, R.
, Petit
, T.
, et al, 2020
, “Nanostructured Boron Doped Diamond Electrodes With Increased Reactivity for Solar-Driven CO2 Reduction in Room Temperature Ionic Liquids
,” ChemCatChem
, 12
(21
), pp. 5548
–5557
. 106.
Butt
, R.
, Siddique
, A. H.
, Bokhari
, S. W.
, Jiang
, S. Q.
, Lei
, D.
, Zhou
, X. F.
, and Liu
, Z. P.
, 2019
, “Niobium Carbide/Reduced Graphene Oxide Hybrid Porous Aerogel as High Capacity and Long-Life Anode Material for Li-Ion Batteries
,” Int. J. Energy Res.
, 43
(9
), pp. 4995
–5003
. 107.
Kamysbayev
, V.
, Filatov
, A. S.
, Hu
, H.
, Rui
, X.
, Lagunas
, F.
, Wang
, D.
, Klie
, R. F.
, and Talapin
, D. V.
, 2020
, “Covalent Surface Modifications and Superconductivity of Two-Dimensional Metal Carbide Mxenes
,” Science
, 369
(6506
), pp. 979
–983
. 108.
Jiwanti
, P. K.
, Alfaza
, A. M.
, Kadja
, G. T. M.
, Khalil
, M.
, and Einaga
, Y.
, 2022
, “Electrochemical Study of CO2 Reduction on Ti3C2Tx Modified Boron-Doped Diamond Electrode
,” Inorg. Chem. Commun.
, 137
(5
), p. 109229
. 109.
Kiat
, S.
, and Samuel
, J.
, 2021
, “Mitigating Iron-Induced Catalytic Wear in Monocrystalline Diamond Tools Using Two-Dimensional (2d) Materials
,” J. Manuf. Process.
, 68
(10
), pp. 95
–103
. 110.
Mirabedini
, P. S.
, Debnath
, B.
, Neupane
, M. R.
, Greaney
, P. A.
, Birdwell
, A. G.
, Ruzmetov
, D.
, Crawford
, K. G.
, Shah
, P.
, Weil
, J.
, and Ivanov
, T. G.
, 2020
, “Structural and Electronic Properties of 2d (Graphene, hbn)/h-Terminated Diamond (100) Heterostructures
,” Appl. Phys. Lett.
, 117
(12
), p. 121901
. 111.
Yang
, D.
, Zhu
, Q.
, and Han
, B.
, 2020
, “Electroreduction of CO2 in Ionic Liquid-Based Electrolytes
,” Innovation
, 1
(1
), p. 100016
. 112.
Wang
, Y.
, Cao
, L.
, Libretto
, N. J.
, Li
, X.
, Li
, C.
, Wan
, Y.
, He
, C.
, et al, 2019
, “Ensemble Effect in Bimetallic Electrocatalysts for CO2 Reduction
,” J. Am. Chem. Soc.
, 141
(42
), pp. 16635
–16642
. 113.
Yang
, N.
, Swain
, G. M.
, and Jiang
, X.
, 2016
, “Nanocarbon Electrochemistry and Electroanalysis: Current Status and Future Perspectives
,” Electroanalysis
, 28
(1
), pp. 27
–34
. 114.
Fernandes
, D.
, Peixoto
, A.
, and Freire
, C.
, 2019
, “Nitrogen Doped Metal Free Carbon Catalysts for (Electro)Chemical CO2 Conversion and Valorisation
,” Dalton Trans.
, 48
(36
), pp. 13508
–13528
. 115.
Zeng
, A.
, Neto
, V. F.
, Gracio
, J. J.
, and Fan
, Q. H.
, 2014
, “Diamond-Like Carbon (DLC) Films as Electrochemical Electrodes
,” Diamond Relat. Mater.
, 43
, pp. 12
–22
. 116.
Hevia
, S. A.
, Bejide
, M.
, Duran
, B.
, Rosenkranz
, A.
, Ruiz
, H. M.
, Favre
, M.
, and del Rio
, R.
, 2018
, “Nanometric Thin Films of Non-Doped Diamond-Like Carbon Grown on n-Type (p-Doped) Silicon Substrates as Electrochemical Electrodes
,” J. Solid State Electrochem.
, 22
(9
), pp. 2845
–2853
. 117.
Baran
, E.
, Baz
, Z.
, Esen
, R.
, and Devrim
, B. Y.
, 2017
, “TiO2-NT Electrodes Modified With Ag and Diamond Like Carbon (DLC) for Hydrogen Production by Alkaline Water Electrolysis
,” Appl. Surf. Sci.
, 420
, pp. 416
–428
. 118.
Hernández
, R. M.
, Márquez
, J.
, Márquez
, O. P.
, Choy
, M.
, Ovalles
, C.
, Garcia
, J. J.
, and Scharifker
, B.
, 1999
, “Reduction of Carbon Dioxide on Modified Glassy Carbon Electrodes
,” J. Electrochem. Soc.
, 146
(11
), pp. 4131
–4136
. 119.
Wang
, Y.
, Qu
, J.
, Li
, S.
, Dong
, Y.
, and Qu
, J.
, 2015
, “Simultaneous Determination of Hydroquinone and Catechol Using a Glassy Carbon Electrode Modified With Gold Nanoparticles, zns/nis@zns Quantum Dots and l-Cysteine
,” Microchim. Acta
, 182
(13
), pp. 2277
–2283
. 120.
Chen
, Z.
, Mou
, K.
, Yao
, S.
, and Liu
, L.
, 2018
, “Highly Selective Electrochemical Reduction of CO2 to Formate on Metal-Free Nitrogen-Doped PC61BM
,” J. Mater. Chem. A
, 6
(24
), pp. 11236
–11243
. 121.
Gao
, Z.
, Li
, J.
, Zhang
, Z.
, and Hu
, W.
, 2022
, “Recent Advances in Carbon-Based Materials for Electrochemical CO2 Reduction Reaction
,” Chin. Chem. Lett.
, 33
(5
), pp. 2270
–2280
. 122.
Sato
, S.
, Arai
, T.
, and Morikawa
, T.
, 2018
, “Electrocatalytic CO2 Reduction Near the Theoretical Potential in Water Using Ru Complex Supported on Carbon Nanotubes
,” Nanotechnology
, 29
(3
), p. 034001
. 123.
Zhang
, C.
, Chen
, H. M.
, Ding
, X. H.
, Lorestani
, F.
, Huang
, C. L.
, Zhang
, B. W.
, Zheng
, B.
, Wang
, J.
, Cheng
, H. Y.
, and Xu
, Y.
, 2022
, “Human Motion-Driven Self-Powered Stretchable Sensing Platform Based on Laser-Induced Graphene Foams
,” Appl. Phys. Rev.
, 9
(1
), p. 011413
. 124.
Wu
, J.
, Liu
, M.
, Sharma
, P. P.
, Yadav
, R. M.
, Ma
, L.
, Yang
, Y.
, Zou
, X.
, et al, 2016
, “Incorporation of Nitrogen Defects for Efficient Reduction of CO2 Via Two-Electron Pathway on Three-Dimensional Graphene Foam
,” Nano Lett.
, 16
(1
), pp. 466
–470
. 125.
Saeidi
, N.
, Esrafili
, M. D.
, and Jahanbin Sardroodi
, J.
, 2022
, “Electrochemical Reduction of No Catalyzed by Boron-Doped c60 Fullerene: A First-Principles Study
,” RSC Adv.
, 12
(5
), pp. 3003
–3012
. 126.
Kao
, W. H.
, Wu
, S. Y.
, and Chen
, H. T.
, 2019
, “Exploring Reaction Mechanisms for Co Oxidation on Boron-Doped Carbon Nanotubes: A Computational Approach
,” Appl. Surf. Sci.
, 480
, pp. 63
–69
. 127.
Sreekanth
, N.
, Nazrulla
, M. A.
, Vineesh
, T. V.
, Sailaja
, K.
, and Phani
, K. L.
, 2015
, “Metal-Free Boron-Doped Graphene for Selective Electroreduction of Carbon Dioxide to Formic Acid/Formate
,” Chem. Commun.
, 51
(89
), pp. 16061
–16064
. 128.
Jia
, C.
, Ren
, W.
, Chen
, X.
, Yang
, W.
, and Zhao
, C.
, 2020
, “(N, B) Dual Heteroatom-Doped Hierarchical Porous Carbon Framework for Efficient Electroreduction of Carbon Dioxide
,” ACS Sustain. Chem. Eng.
, 8
(15
), pp. 6003
–6010
. 129.
Zhu
, J. L.
, Wei
, P. C.
, Key
, J.
, Yin
, S. B.
, Ma
, S. J.
, and Shen
, P. K.
, 2019
, “Self-Assembled and Well Separated B and N Co-Doped Hierarchical Carbon Structures as High-Capacity, Ultra-Stable, LIB Anode Materials
,” Sustain. Energy Fuels
, 3
(2
), pp. 478
–487
. 130.
Li
, R.
, 2005
, “A Molecular Dynamics Study of Boron and Nitrogen in Diamond
,” Solid State Commun.
, 135
(3
), pp. 155
–157
. 131.
Lee
, S.
, and Lee
, J.
, 2016
, “Electrode Build-Up of Reducible Metal Composites Toward Achievable Electrochemical Conversion of Carbon Dioxide
,” ChemSusChem
, 9
(4
), pp. 333
–344
. 132.
Zhao
, X.
, Luo
, B.
, Long
, R.
, Wang
, C.
, and Xiong
, Y.
, 2015
, “Composition-Dependent Activity of Cu-Pt Alloy Nanocubes for Electrocatalytic CO2 Reduction
,” J. Mater. Chem. A
, 3
(8
), pp. 4134
–4138
. 133.
Mavrokefalos
, C. K.
, Nelson
, G. W.
, Poll
, C. G.
, Compton
, R. G.
, and Foord
, J. S.
, 2015
, “Electrochemical Aspects of Pt-Cu and Cu Modified Boron-Doped Diamond
,” Phys. Status Solidi A
, 212
(11
), pp. 2559
–2567
. 134.
Rasul
, S.
, Anjum
, D. H.
, Jedidi
, A.
, Minenkov
, Y.
, Cavallo
, L.
, and Takanabe
, K.
, 2015
, “A Highly Selective Copper-Indium Bimetallic Electrocatalyst for the Electrochemical Reduction of Aqueous CO2 to CO
,” Angew. Chem. Int. Ed.
, 54
(7
), pp. 2146
–2150
. 135.
Jia
, F.
, Yu
, X.
, and Zhang
, L.
, 2014
, “Enhanced Selectivity for the Electrochemical Reduction of CO2 to Alcohols in Aqueous Solution With Nanostructured Cu-Au Alloy as Catalyst
,” J. Power Sources
, 252
, pp. 85
–89
. 136.
Baek
, Y.
, Song
, H.
, Hong
, D.
, Wang
, S.
, Lee
, S.
, Joo
, Y.-C.
, Lee
, G.-D.
, and Oh
, J.
, “Electrochemical Carbon Dioxide Reduction on Copper-Zinc Alloys: Ethanol and Ethylene Selectivity Analysis
,” J. Mater. Chem. A
, 10
(17
), pp. 9393
–9401
. 137.
Mavrokefalos
, C. K.
, Hasan
, M.
, Khunsin
, W.
, Schmidt
, M.
, Maier
, S. A.
, Rohan
, J. F.
, Compton
, R. G.
, and Foord
, J. S.
, 2017
, “Electrochemically Modified Boron-Doped Diamond Electrode With Pd and Pd-Sn Nanoparticles for Ethanol Electrooxidation
,” Electrochim. Acta
, 243
, pp. 310
–319
. 138.
Kumik
, A.
, Ivandini
, T. A.
, and Wibowo
, R.
, 2020
, “Modification of Boron-Doped Diamond With Gold-Palladium Nanoparticles for CO2 Electroreduction
,” IOP Conf. Ser.: Mater. Sci. Eng.
, 763
(1
), p. 012001
. 139.
Jian
, Z.
, Xu
, J.
, Yang
, N.
, Han
, S.
, and Jiang
, X.
, 2021
, “A Perspective on Diamond Composites and Their Electrochemical Applications
,” Curr. Opin. Electrochem.
, 30
, p. 100835
. 140.
Birdja
, Y.
, Pérez-Gallent
, E.
, Figueiredo
, M.
, Göttle
, A.
, Calle-Vallejo
, F.
, and Koper
, M.
, 2019
, “Advances and Challenges in Understanding the Electrocatalytic Conversion of Carbon Dioxide to Fuels
,” Nat. Energy
, 4
(9
), pp. 732
–745
. 141.
Agarwal
, A.
, Zhai
, Y.
, Hill
, D.
, and Sridhar
, N.
, 2011
, “The Electrochemical Reduction of Carbon Dioxide to Formate/Formic Acid: Engineering and Economic Feasibility
,” ChemSusChem
, 4
(9
), pp. 1301
–1310
. 142.
Gong
, Q.
, Ding
, P.
, Xu
, M.
, Zhu
, X.
, Wang
, M.
, Deng
, J.
, Ma
, Q.
, et al, 2019
, “Structural Defects on Converted Bismuth Oxide Nanotubes Enable Highly Active Electrocatalysis of Carbon Dioxide Reduction
,” Nat. Commun.
, 10
(1
), p. 2807
. 143.
Li
, D.
, Zhang
, H.
, Xiang
, H.
, Rasul
, S.
, Fontmorin
, J. M.
, Izadi
, P.
, Roldan
, A.
, et al, 2021
, “How to Go Beyond C-1 Products With Electrochemical Reduction of CO2
,” Sustain. Energy Fuels
, 5
(23
), pp. 5893
–5914
. 144.
Dongare
, S.
, Singh
, N.
, Bhunia
, H.
, Bajpai
, P. K.
, and Das
, A. K.
, 2021
, “Electrochemical Reduction of Carbon Dioxide to Ethanol: A Review
,” ChemistrySelect
, 6
(42
), pp. 11603
–11629
. 145.
Liu
, Y.
, Zhang
, Y.
, Cheng
, K.
, Quan
, X.
, Fan
, X.
, Su
, Y.
, Chen
, S.
, et al, 2017
, “Selective Electrochemical Reduction of Carbon Dioxide to Ethanol on a Boron- and Nitrogen-Co-Doped Nanodiamond
,” Angew. Chem. Int. Ed.
, 56
(49
), pp. 15607
–15611
. 146.
Liu
, Y.
, Yang
, H.
, Fan
, X.
, Shan
, B.
, and Meyer
, T. J.
, 2022
, “Promoting Electrochemical Reduction of CO2 to Ethanol by b/n-Doped sp3/sp2 Nanocarbon Electrode
,” Chin. Chem. Lett.
, 33
(10
), pp. 4691
–4694
. 147.
Pander
, J. E.
III
, Ren
, D.
, Huang
, Y.
, Loo
, N. W. X.
, Hong
, S. H. L.
, and Yeo
, B. S.
, 2018
, “Understanding the Heterogeneous Electrocatalytic Reduction of Carbon Dioxide on Oxide-Derived Catalysts
,” ChemElectroChem
, 5
(2
), pp. 219
–237
. 148.
Jiwanti
, P. K.
, Natsui
, K.
, Nakata
, K.
, and Einaga
, Y.
, 2018
, “The Electrochemical Production of C2/C3 Species From Carbon Dioxide on Copper-Modified Boron-Doped Diamond Electrodes
,” Electrochim. Acta
, 266
, pp. 414
–419
. 149.
Denala
, D.
, Khalil
, M.
, and Ivandini
, T. A.
, 2019
, “Preparation of Boron Doped Diamond Modified With Cuprous Oxide as Working Electrode for Electroreduction of CO2
,” AIP Conf. Proc.
, 2168
(1
), p. 020057
. 150.
Zahid
, A.
, Shah
, A.
, and Shah
, I.
, 2022
, “Oxide Derived Copper for Electrochemical Reduction of CO2 to C2 + Products
,” Nanomaterials
, 12
(8
), p. 1380
. 151.
Nihongi
, S.
, Otake
, A.
, Du
, J.
, and Einaga
, Y.
, 2022
, “Convection Control in a Flow Cell on Electrochemical CO2 Reduction Using a Boron-Doped Diamond Electrode
,” Carbon
, 200
, pp. 456
–461
. 152.
Dinh
, C. T.
, Burdyny
, T.
, Kibria
, M. G.
, Seifitokaldani
, A.
, Gabardo
, C. M.
, García de Arquer
, F. P.
, Kiani
, A.
, et al, 2018
, “CO2 Electroreduction to Ethylene Via Hydroxide-Mediated Copper Catalysis at an Abrupt Interface
,” Science
, 360
(6390
), pp. 783
–787
. 153.
Li
, Y. C.
, Wang
, Z.
, Yuan
, T.
, Nam
, D. H.
, Luo
, M.
, Wicks
, J.
, Chen
, B.
, et al, 2019
, “Binding Site Diversity Promotes CO2 Electroreduction to Ethanol
,” J. Am. Chem. Soc.
, 141
(21
), pp. 8584
–8591
. 154.
Huang
, Y.
, Handoko
, A. D.
, Hirunsit
, P.
, and Yeo
, B. S.
, 2017
, “Electrochemical Reduction of CO2 Using Copper Single-Crystal Surfaces: Effects of CO* Coverage on the Selective Formation of Ethylene
,” ACS Catal.
, 7
(3
), pp. 1749
–1756
. 155.
Gabardo
, C. M.
, O’Brien
, C. P.
, Edwards
, J. P.
, McCallum
, C.
, Xu
, Y.
, Dinh
, C.-T.
, Li
, J.
, Sargent
, E. H.
, and Sinton
, D.
, 2019
, “Continuous Carbon Dioxide Electroreduction to Concentrated Multi-Carbon Products Using a Membrane Electrode Assembly
,” Joule
, 3
(11
), pp. 2777
–2791
. 156.
Tomisaki
, M.
, Natsui
, K.
, Ikemiya
, N.
, Nakata
, K.
, and Einaga
, Y.
, 2018
, “Influence of Electrolyte on the Electrochemical Reduction of Carbon Dioxide Using Boron-Doped Diamond Electrodes
,” ChemistrySelect
, 3
(36
), pp. 10209
–10213
. 157.
Yang
, W.
, Chen
, S.
, Ren
, W.
, Zhao
, Y.
, Chen
, X.
, Jia
, C.
, Liu
, J.
, and Zhao
, C.
, 2019
, “Nanostructured Amalgams With Tuneable Silver-Mercury Bonding Sites for Selective Electroreduction of Carbon Dioxide Into Formate and Carbon Monoxide
,” J. Mater. Chem. A
, 7
(26
), pp. 15907
–15912
. 158.
le Sache
, E.
, Pastor-Perez
, L.
, Haycock
, B. J.
, Jose Villora-Pico
, J.
, Sepulveda-Escribano
, A.
, and Reina
, T. R.
, 2020
, “Switchable Catalysts for Chemical CO2 Recycling: A Step Forward in the Methanation and Reverse Water-Gas Shift Reactions
,” ACS Sustain. Chem. Eng.
, 8
(11
), pp. 4614
–4622
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