Due to the limited temperature resistance, the deep conformance control technology of using the conventional hydrolyzed polyacrylamide (HPAM) gel failed to enhance oil recovery in high-temperature heterogeneous oil reservoirs. Therefore, it is necessary to develop a gelant with high temperature resistance to meet the demands of increasing oil production and decreasing water cut in high-temperature heterogeneous oil reservoirs. In this paper, a copolymer is first synthesized by the method of inverse emulsion polymerization using 2-acrylamide-2-tetradecyl ethyl sulfonic acid (AMC16S), acrylamide (AM), and acrylic acid (AA). The developed copolymer has a highly branching skeleton and can resist temperature up to 100 °C. And then, a gelant with high temperature resistance and good shear resistance can be formed by mixing a certain proportion of the developed copolymer and polyethyleneimine (PEI). After the controllable gelation, a copolymer gel is formed and the formed gel can maintain the stable performance for a long time in the high-temperature environment. Experimental results show that the developed gelant can be applied in the conformance control of high-temperature heterogeneous oil reservoir.

References

1.
Zhang
,
J.
,
He
,
H.
,
Wang
,
Y. F.
,
Xu
,
X. L.
,
Zhu
,
Y. J.
, and
Li
,
R. Y.
,
2014
, “
Gelation Performance and Microstructure Study of Chromium Gel and Phenolic Resin Gel in Bulk and Porous Media
,”
ASME J. Energy Resour. Technol.
,
136
(
4
), p.
042910
.
2.
Zhang
,
L.
,
Pu
,
C.
,
Cui
,
S.
,
Nasir
,
K.
, and
Liu
,
Y.
,
2017
, “
Experimental Study on a New Type of Water Shutoff Agent Used in Fractured Low Permeability Reservoir
,”
ASME J. Energy Resour. Technol.
,
139
(
1
), p.
012907
.
3.
Chen
,
X. C.
,
Feng
,
Q. H.
, and
Wang
,
Q.
,
2014
, “
Performance Prediction of Gel Water Shutoff in Horizontal Wells Using a Newly Coupled Reservoir-Wellbore Model
,”
ASME J. Energy Resour. Technol.
,
136
(
2
), p.
022903
.
4.
He
,
H.
,
Wang
,
Y.
,
Qi
,
Z.
, and
Sun
,
X.
,
2017
, “
Gelation Performance and Feasibility Study of an Environmental Friendly Improved Inorganic Aluminum Gel for Conformance Control Under Harsh Reservoir Conditions
,”
ASME J. Energy Resour. Technol.
,
139
(
1
), p.
012911
.
5.
Wang
,
C.
,
Liu
,
H.
,
Zheng
,
Q.
,
Liu
,
Y.
,
Dong
,
X.
, and
Hong
,
C.
,
2016
, “
A New High-Temperature Gel for Profile Control in Heavy Oil Reservoirs
,”
ASME J. Energy Resour. Technol.
,
138
(
2
), p.
022901
.
6.
Dai
,
C.
,
You
,
Q.
,
He
,
L.
, and
Zhao
,
F.
,
2012
, “
Study and Field Application of a Profile Control Agent in a High Temperature and High Salinity Reservoir
,”
J. Energy Source Part A
,
34
(
1
), pp.
53
63
.
7.
Chen
,
W.
,
Qiu
,
H.
, and
Cui
,
S.
,
2013
, “
High-Temperature Resistance Performance of an Inorganic Adhesive for Concrete Structures Strengthened With CFRP Sheets
,”
J. Wuhan Univ. Technol., Mater. Sci. Ed.
,
28
(
5
), pp.
950
954
.
8.
Zhang
,
L.
,
Pu
,
C.
,
Sang
,
H.
, and
Zhao
,
Q.
,
2015
, “
Mechanism Study of the Cross-Linking Reaction of Hydrolyzed Polyacrylamide/Ac3Cr in Formation Water
,”
Energy Fuels
,
29
(8), pp.
4701
4710
.
9.
Jin
,
F. Y.
,
Yuan
,
C. D.
, and
Pu
,
W. F.
,
2015
, “
Investigation on Gelation Process and Microstructure for Partially Hydrolyzed Polyacrylic Amide (HPAm)–Cr (III) Acetate–Methanol Compound Crosslinked Weak Gel
,”
J. Sol-Gel Sci. Technol.
,
73
(1), pp.
181
191
.
10.
Xin
,
H.
,
Chen
,
H.
,
Wang
,
X.
,
Zhang
,
J.
, and
Tan
,
Y.
,
2013
, “
Fabrication of the Weak Gel Based on Hydrolyzed Polyacrylamide Crosslinked by Inorganic-Organic Mixed Crosslinker
,”
J. Polym. Res.
,
20
(
12
), pp.
311
316
.
11.
Wang
,
D. H.
,
Im
,
S. H.
,
Lee
,
H. K.
,
Park
,
O. O.
, and
Park
,
J. H.
,
2009
, “
Enhanced High-Temperature Long-Term Stability of Polymer Solar Cells With a Thermally Stable TiOx Interlayer
,”
J. Phys. Chem. C
,
113
(39), pp.
17268
17273
.
12.
Luo
,
H.
,
Chen
,
D.
,
Yang
,
X.
,
Zhao
,
X.
,
Feng
,
H.
,
Li
,
M.
, and
Wang
,
J.
,
2015
, “
Synthesis and Performance of a Polymeric Scale Inhibitor for Oilfield Application
,”
J. Pet. Explor. Prod. Tech.
,
5
(2), pp.
177
187
.
13.
Cao
,
J.
,
Tan
,
Y.
,
Che
,
Y.
, and
Ma
,
Q.
,
2011
, “
Synthesis of Copolymer of Acrylamide With Sodium Vinylsulfonate and Its Thermal Stability in Solution
,”
J. Polym. Res.
,
18
(2), pp.
171
178
.
14.
Meister
,
J. J.
,
1988
,
Water-Soluble Polymers for Petroleum Recovery
,
Springer
,
New York
.
15.
Myagchenkov
,
V. A.
, and
Chichkanov
,
S. V.
,
2003
, “
Influence of Concentration and Molecular Characteristics of Copolymers of Acrylamide With Sodium Acrylate on the Thoms Effect in Oil-in-Water Emulsions
,”
Russ. J. Appl. Chem.
,
76
(
11
), pp.
1850
1854
.
16.
Bu
,
H.
,
Sun
,
J.
,
Wang
,
C.
, and
Bu
,
P.
,
2013
, “
Rheological Properties of Polymer-Gel Drilling Fluids at High Temperature and Pressure
,”
Chem. Technol. Fuel Oil
,
48
(6), pp.
449
458
.
17.
Jia
,
H.
,
Pu
,
W. F.
,
Zhao
,
J. Z.
, and
Jin
,
F. Y.
,
2010
,
Ind. Eng. Chem. Res.
,
49
(20), pp.
9618
9624
.
18.
Jia
,
H.
,
Zhao
,
J. Z.
,
Jin
,
F. Y.
,
Pu
,
W. F.
,
Li
,
Y. M.
,
Li
,
K. X.
, and
Li
,
J. M.
,
2012
, “
Research on the Gelation Performance of Low Toxic PEI Cross-Linking PHPAM Gel Systems as Water Shutoff Agents in Low Temperature Reservoirs
,”
Ind. Eng. Chem. Res.
,
51
(38), pp.
12155
12166
.
19.
Kamal
,
M. S.
,
Sultan
,
A. S.
,
Al-Mubaiyedh
,
U. A.
, and
Hussein
,
I. A.
,
2015
, “
Review on Polymer Flooding: Rheology, Adsorption, Stability, and Field Applications of Various Polymer Systems
,”
Polym. Rev.
,
55
(3), pp.
491
530
.
20.
Han
,
M.
,
Zhou
,
X.
,
Fuseni
,
A.
,
Al-Zahrani
,
B.
, and
AlSofi
,
A.
,
2012
, “
Laboratory Investigation of the Injectivity of Sulfonated Polyacrylamide Solutions Into Carbonate Reservoir Rocks
,”
SPE EOR Conference at Oil and Gas West Asia
, Muscat, Oman, Apr. 16–18,
SPE
Paper No. 155390.
21.
Noik
,
C.
,
Audibert
,
A.
, and
Delaplace
,
P.
,
1994
, “
Injectivity of Sulfonated Polymers Under North Sea Field Conditions
,”
SPE/DOE Improved Oil Recovery Symposium
, Tulsa, OK, Apr. 17–20,
SPE
Paper No. 27769.
22.
Rashidi
,
M.
,
Blokhus
,
A. M.
, and
Skauge
,
A.
,
2011
, “
Viscosity and Retention of Sulfonated Polyacrylamide Polymers at High Temperature
,”
J. Appl. Polym. Sci.
,
119
(
6
), pp.
3623
3629
.
23.
Doe
,
P.
,
Moradi-Araghi
,
A.
,
Shaw
,
J.
, and
Stahl
,
G.
,
1987
, “
Development and Evaluation of EOR Polymers Suitable for Hostile Environments—Part 1: Copolymers of Vinylpyrrolidone and Acrylamide
,”
SPE Reserv. Eng.
,
2
(
4
), pp.
461
467
.
24.
Kulawardana
,
E. U.
,
Koh
,
H.
,
Kim
,
D. H.
,
Liyanage
,
P. J.
,
Upamali
,
K.
,
Huh
,
C.
,
Weerasooriya
,
U.
, and
Pope
,
G.
,
2012
, “
Rheology and Transport of Improved EOR Polymers Under Harsh Reservoir Conditions
,”
SPE Improved Oil Recovery Symposium
, Tulsa, OK, Apr. 14–18,
SPE
Paper No. 154294.
25.
Kiatkamjornwong
,
S.
, and
Suwanmala
,
P.
,
1998
, “
Partially Hydrolyzed Polyacrylamide–Poly (N-Vinylpyrrolidone) Copolymers as Superabsorbents Synthesized by Gamma Irradiation
,”
J. Appl. Polym. Sci.
,
68
(
2
), pp.
191
203
.
26.
Gaillard
,
N.
,
Sanders
,
D. B.
, and
Favero
,
C.
,
2010
, “
Improved Oil Recovery Using Thermally and Chemically Protected Compositions Based on Co-and Terpolymers Containing Acrylamide
,”
SPE Improved Oil Recovery Symposium
, Tulsa, OK, Apr. 24–28,
SPE
Paper No. 129756.
27.
Chen
,
H.
,
Wang
,
Z. M.
,
Ye
,
Z. B.
, and
Han
,
L. J.
,
2014
, “
The Solution Behavior of Hydrophobically Associating Zwitterionic Polymer in Salt Water
,”
J. Appl. Polym. Sci.
,
131
(
1
), p.
39707
.
28.
Ye
,
Z. B.
,
He
,
E. Q.
,
Xie
,
S. Y.
,
Han
,
L. J.
,
Chen
,
H.
,
Luo
,
P. Y.
,
Shu
,
Z.
,
Shi
,
L. T.
, and
Lai
,
N. J.
,
2010
, “
The Mechanism Study of Disproportionate Permeability Reduction by Hydrophobically Associating Water-Soluble Polymer Gel
,”
J. Pet. Sci. Eng.
,
72
(1–2), pp.
64
66
.
29.
Lahalih
,
S. M.
, and
Ghloum
,
E. F.
,
2007
, “
Rheological Properties of New Polymer Compositions for Sand Consolidation and Water Shutoff in Oil Wells
,”
J. Appl. Polym. Sci.
,
104
, pp.
2076
2087
.
30.
Kuang
,
W.
, and
Xia
,
Y.
,
2014
, “
A Novel Dendritic-Like Terpolymer as a Viscosifying Additive for Enhanced Oil Recovery
,”
Mater. Lett.
,
115
, pp.
109
112
.
31.
Langlotz
,
B. R.
,
Brodt
,
G.
,
Reichenbach-Klinke
,
R.
,
Stavland
,
A.
,
Langlotz
,
B. R.
,
Wenzke
,
B.
, and
Brodt
,
G.
,
2013
, “
New Insights Into the Mechanism of Mobility Reduction by Associative Type Copolymers
,”
SPE Enhanced Oil Recovery Conference
, Kuala Lumpur, Malaysia, July 2–4,
SPE
Paper No. 165225.
32.
Zhang
,
P.
,
Wang
,
Y.
,
Yang
,
Y.
,
Zhang
,
J.
,
Cao
,
X.
, and
Song
,
X.
,
2012
, “
The Effect of Microstructure on Performance of Associative Polymer: In Solution and Porous Media
,”
J. Pet. Sci. Eng.
,
90–91
, pp.
12
17
.
33.
Shepitka
,
J. S.
,
Case
,
C. E.
,
Donaruma
,
L. G.
,
Hatch
,
M. J.
,
Kilmer
,
N. H.
,
Khune
,
G. D.
,
Martin
,
F. D.
,
Ward
,
J. S.
, and
Wilson
,
K. V.
,
1983
, “
Partially Imidized, Water-Soluble Polymeric Amides—I: Partially Imidized Polyacrylamide and Polymethacrylamide
,”
J. Appl. Polym. Sci.
,
28
(
12
), pp.
3611
3617
.
34.
Uhl
,
J. T.
,
Ching
,
T. Y.
, and
Bae
,
J. H.
,
1995
, “
A Laboratory Study of New, Surfactant-Containing Polymers for High-Salinity Reservoirs
,”
SPE Adv. Technol. Ser.
,
3
(
1
), pp.
113
119
.
35.
Zhu
,
Y.
,
Wang
,
Z.
,
Wu
,
K.
,
Hou
,
Q.
, and
Long
,
H.
,
2013
, “
Enhanced Oil Recovery by Chemical Flooding From the Biostromal Carbonate Reservoir
,”
SPE Enhanced Oil Recovery Conference
, Kuala Lumpur, Malaysia, July 2–4,
SPE
Paper No. 165208.
36.
Zhao
,
Y.
,
Zhou
,
J.
,
Xu
,
X.
,
Liu
,
W.
,
Zhang
,
J.
,
Fan
,
M.
, and
Wang
,
J.
,
2009
, “
Synthesis and Characterization of a Series of Modified Polyacrylamide
,”
Colloid Polym. Sci.
,
287
(
2
), pp.
237
241
.
37.
Zhou
,
C.
,
Yang
,
W.
,
Yu
,
Z.
,
Zhou
,
W.
,
Xia
,
Y.
,
Han
,
Z.
, and
Wu
,
Q.
,
2011
, “
Synthesis and Solution Properties of Novel Comb-Shaped Acrylamide Copolymers
,”
Polym. Bull.
,
66
(
3
), pp.
407
417
.
38.
Luo
,
X.
,
Bai
,
L.
,
Za
,
K.
,
Li
,
D.
,
Han
,
W.
, and
Pu
,
X.
,
2012
, “
Synthesis and Solution Properties of Comb-Like Acrylamide Copolymers
,”
J. Wuhan Univ. Technol.
,
27
(
6
), pp.
1105
1109
.
39.
Liu
,
X. J.
,
Jiang
,
W. C.
,
Gou
,
S. H.
,
Ye
,
Z. B.
, and
Xie
,
X. D.
,
2012
, “
Synthesis and Evaluation of a Water-Soluble Acrylamide Binary Sulfonates Copolymer on MMT Crystalline Interspace and EOR
,”
J. Appl. Polym. Sci.
,
125
(
2
), pp.
1252
1260
.
40.
Ye
,
Z.
,
Gou
,
G.
,
Gou
,
S.
,
Jiang
,
W.
, and
Liu
,
T.
,
2013
, “
Synthesis and Characterization of a Water-Soluble Sulfonates Copolymer of Acrylamide and N-Allylbenzamide as Enhanced Oil Recovery Chemical
,”
J. Appl. Polym. Sci.
,
128
(
3
), pp.
2003
2011
.
41.
Wang
,
F.
,
Wang
,
C.
,
Zhu
,
Z.
,
Ouyang
,
J.
,
Chen
,
G.
, and
Wang
,
Y.
,
2015
, “
Synthesis and Solution Properties of NaAMC16S/AM/AA Terpolymer
,”
Oilfield Chem.
,
32
(
3
), pp.
366
369
(in Chinese).
42.
Jia
,
H.
,
Pu
,
W. F.
,
Zhao
,
J. Z.
, and
Liao
,
R.
,
2011
, “
Experimental Investigation of the Novel Phenol−Formaldehyde Cross-Linking HPAM Gel System: Based on the Secondary Cross-Linking Method of Organic Cross-Linkers
,”
Energy Fuels
,
25
(2), pp.
727
736
.
43.
Sabhapondit
,
A.
,
Borthakur
,
A.
, and
Haque
,
I.
,
2003
, “
Water Soluble Acrylamidomethyl Propane Sulfonate (AMPS) Copolymer as an Enhanced Oil Recovery Chemical
,”
Energy Fuels
,
17
(3), pp.
683
688
.
44.
Zou
,
C.
,
Zhao
,
P.
,
Hu
,
X.
,
Yan
,
X.
,
Zhang
,
Y.
,
Wang
,
X.
,
Song
,
R.
, and
Luo
,
P.
,
2013
, “
β-Cyclodextrin-Functionalized Hydrophobically Associating Acrylamide Copolymer for Enhanced Oil Recovery
,”
Energy Fuels
,
27
(5), pp.
2827
2834
.
45.
Moradi-Araghi
,
A.
,
2000
, “
A Review of Thermally Stable Gels for Fluid Diversion in Petroleum Production
,”
J. Pet. Sci. Eng.
,
26
(1–4), pp.
1
10
.
46.
Bai
,
Y.
,
Xiong
,
C.
,
Wei
,
F.
,
Li
,
J.
,
Shu
,
Y.
, and
Liu
,
D.
,
2015
, “
Gelation Study on a Hydrophobically Associating Polymer/Polyethylenimine Gel System for Water Shut-Off Treatment
,”
Energy Fuels
,
29
(
2
), pp.
447
458
.
47.
Zhao
,
G.
,
Dai
,
C.
,
Zhao
,
M.
, and
You
,
Q.
,
2014
, “
The Use of Environmental Scanning Electron Microscopy for Imaging the Microstructure of Gels for Profile Control and Water Shutoff Treatments
,”
J. Appl. Polym. Sci.
,
131
(
4
), p.
39946
.
You do not currently have access to this content.